Home
Class 12
CHEMISTRY
Write equations for the steps in S(N)1 m...

Write equations for the steps in `S_(N)1` mechanism of conversion of tertiary butyl bromide into tertiary butyl alcohol.

Text Solution

Verified by Experts

a) The mechanisminvolves the following two steps.
Step 1:
Formation of carbocation: t-butyl bromide undergoes ionization to form a t-butyl carbocation.

This step is the slowest stephence it is the rate determining step.
Step-2:
Attack of nucleophile on the carbocation : The nucleophile `OH^(-)` can attack the carbocation either from front side or back side to form t - butyl alcohol. The step is fast.

`therefore` Rate of the reaction is directly `alpha" [t - butyl bromide]"^(1)[OH-]^(0)`
`therefore"  Order = 1"`
Promotional Banner

Topper's Solved these Questions

  • II PUC CHEMISTRY (ANNUAL EXAM QUESTION PAPER MARCH - 2015)

    SUNSTAR PUBLICATION|Exercise PART - C|8 Videos
  • II PUC CHEMISTRY (ANNUAL EXAM QUESTION PAPER MARCH - 2014)

    SUNSTAR PUBLICATION|Exercise PART - D|22 Videos
  • II PUC CHEMISTRY (ANNUAL EXAM QUESTION PAPER MARCH - 2016)

    SUNSTAR PUBLICATION|Exercise PART - D|26 Videos

Similar Questions

Explore conceptually related problems

a) i) write the equations for the steps in SN1 mechanism of the conversion of tertiary butyl bromide in to tertiary butyl alcohol. ii) Haloarenes are less reactive towards nucleophilic substitution reactions than Haloalkanes. Give a reason.

Write equations for the steps in SN^1 mechanism of the conversion of tert.butyl bromide into tert.butyl alcohol.

Write the equations for the steps in SN-1 mechanism of the convertion of tert-Butyl bromide into tert-butyl alcohol.

Write steps involved in S_(N)1 mechanism to the conversion of tertiary butyl bromide into tertiary butyl alcohol and mention its order.

(a) Write the equations for the steps involved in SN^(1) mechanism for the conversion of tert-butyl bromide to tert-butyl alcohol.

Write the equations for the steps in SN^(1) mechanism of the conversion of the conversion of tert -butyl bromide into tert-butyl alcohol.

(a) Explain S_(N)1 mechanism for the conversion of tertiary butyl bromide to tertiary butyl alcohol. (b) Complete the following reactions : (i) CH_(3) - CH = CH_(2) + HI rarr (ii) (iii) CH_(3)CH_(2)Br underset("Aq Ethanol")overset(AgCN)rarr

Write SN^(2) mechanism of the conversion of methyl chloride to methyl alcohol.

SUNSTAR PUBLICATION-II PUC CHEMISTRY (ANNUAL EXAM QUESTION PAPER MARCH - 2015)-PART - D
  1. Calculate the EMF of the cell for the reaction Mg((s))+2Ag((aq))^(+)...

    Text Solution

    |

  2. What are fuel cells ?

    Text Solution

    |

  3. Derive an intergrated rate for the first order reaction.

    Text Solution

    |

  4. According to collision theory, what are the two factors that lead to e...

    Text Solution

    |

  5. Write any two differences between physisorption and chemisorption.

    Text Solution

    |

  6. Name the phenomenon/effect for the following i) Collidal particles a...

    Text Solution

    |

  7. Write equations for the steps in S(N)1 mechanism of conversion of tert...

    Text Solution

    |

  8. Identify the products A, B and C in the following equation. CH(3)OH ...

    Text Solution

    |

  9. Write the mechanism of acid catalysed dehydration of ethanol to ethene...

    Text Solution

    |

  10. Explain Williamson's reaction. Write the general equation.

    Text Solution

    |

  11. Write the organic compound formed in the following equations. ii)...

    Text Solution

    |

  12. Explain HVZ (Hell-Volhard-Zelinsky) reaction with equation.

    Text Solution

    |

  13. Identified the reactant A in the following reaction : A+4R-X rarr R(...

    Text Solution

    |

  14. Explain Hoffmann bromamide degradation for the preparation of methanam...

    Text Solution

    |

  15. Which is more basic among aqueous solutions of aniline and ammonia ? G...

    Text Solution

    |

  16. Write Haworth structure for maltose.

    Text Solution

    |

  17. What is meant by denaturation of protein ? Which level of structure re...

    Text Solution

    |

  18. Name the base present only in DNA but not in RNA.

    Text Solution

    |

  19. Write the partial structure of i) Neoprene ii) Terylene(Dacron) iii)...

    Text Solution

    |

  20. Explain the preparation of Buna-N with equation.

    Text Solution

    |