The reaction of propene with HBr in the ...

The reaction of propene with HBr in the presence of ROOR (peroxide) proceeds through which of the following intermediates?

A

`CH_3 - overset(*)(CH)-CH_3`

B

`CH_3- overset(*)(CH)-CH_2Br`

C

`CH_3-overset(Br)overset(|)CH_2 - overset(*)CH_3`

D

`CH_3- CH_2- overset(*)(C)H_2`

Text Solution

Verified by Experts

The correct Answer is:

B

The initial reaction in this mechanism will be the reaction of an alkoxy radical with HBr producing an alcohol and bromine radical. The bromine radical then reacts with propene to produce this intermediate

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