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A sample of paramagnetic salt contains 2...

A sample of paramagnetic salt contains `2xx10^(24)` atomic dipoles, each of moment `1.5xx10^(-23)JT^-1`. The sample is placed under a homogeneous magnetic field of `0.64T` and cooled to a temperature of `4.2K`. The degree of magnetic saturation archieved is equal to `15%`. What is the total dipole moment of the sample for a mangetic field of `0.98T` and a temperature of `2.8K`. (Assume Curie's law).

A

`8 xx 10^(3) J//T`

B

` 10.34 J//T`

C

` 8 xx 10 ^(-3) J//T`

D

` 25 J//T`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will follow these steps: ### Step 1: Calculate the total dipole moment of the sample. The total dipole moment \( M_{\text{total}} \) can be calculated using the formula: \[ M_{\text{total}} = N \cdot \mu \] where: - \( N = 2 \times 10^{24} \) (number of atomic dipoles), - \( \mu = 1.5 \times 10^{-23} \, \text{J/T} \) (dipole moment of each atomic dipole). Substituting the values: \[ M_{\text{total}} = (2 \times 10^{24}) \cdot (1.5 \times 10^{-23}) = 30 \, \text{J/T} \] ### Step 2: Calculate the effective magnetic moment at the first condition. Given that the degree of magnetic saturation achieved is \( 15\% \), we can find the effective magnetic moment \( M_{\text{effective}} \) at the first condition (magnetic field \( B_1 = 0.64 \, \text{T} \) and temperature \( T_1 = 4.2 \, \text{K} \)): \[ M_{\text{effective}} = 0.15 \cdot M_{\text{total}} = 0.15 \cdot 30 = 4.5 \, \text{J/T} \] ### Step 3: Apply Curie’s Law to find the constant \( C \). According to Curie’s Law: \[ M_{\text{effective}} = C \cdot \frac{B_1}{T_1} \] We can rearrange this to find \( C \): \[ C = M_{\text{effective}} \cdot \frac{T_1}{B_1} \] Substituting the values: \[ C = 4.5 \cdot \frac{4.2}{0.64} = 29.53 \, \text{J/T}^2 \cdot \text{K} \] ### Step 4: Calculate the effective magnetic moment at the second condition. Now we need to find the effective magnetic moment \( M_{\text{effective}}' \) for the new conditions (magnetic field \( B_2 = 0.98 \, \text{T} \) and temperature \( T_2 = 2.8 \, \text{K} \)): \[ M_{\text{effective}}' = C \cdot \frac{B_2}{T_2} \] Substituting the values: \[ M_{\text{effective}}' = 29.53 \cdot \frac{0.98}{2.8} = 10.34 \, \text{J/T} \] ### Final Answer: The total dipole moment of the sample for a magnetic field of \( 0.98 \, \text{T} \) and a temperature of \( 2.8 \, \text{K} \) is \( 10.34 \, \text{J/T} \). ---
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