Home
Class 12
CHEMISTRY
1.5g of an organic compound in a quantit...

1.5g of an organic compound in a quantitative determination of phosphorus gave 2.5090g of `Mg_(2)P_(2)O_(7)`. Calculate the percentage of phosphorus in the compound

Text Solution

AI Generated Solution

The correct Answer is:
To calculate the percentage of phosphorus in the organic compound based on the provided data, we can follow these steps: ### Step 1: Determine the Molecular Weight of Mg₂P₂O₇ The molecular formula for magnesium pyrophosphate is Mg₂P₂O₇. We need to calculate its molecular weight using the atomic weights of magnesium (Mg), phosphorus (P), and oxygen (O): - Atomic weight of Mg = 24 g/mol - Atomic weight of P = 31 g/mol - Atomic weight of O = 16 g/mol Now, we can calculate the molecular weight of Mg₂P₂O₇: \[ \text{Molecular weight of Mg}_2\text{P}_2\text{O}_7 = (2 \times 24) + (2 \times 31) + (7 \times 16) \] Calculating each component: - For Mg: \(2 \times 24 = 48\) - For P: \(2 \times 31 = 62\) - For O: \(7 \times 16 = 112\) Now, add them together: \[ \text{Molecular weight of Mg}_2\text{P}_2\text{O}_7 = 48 + 62 + 112 = 222 \text{ g/mol} \] ### Step 2: Determine the Weight of Phosphorus in Mg₂P₂O₇ Next, we need to find out how much phosphorus is present in the compound Mg₂P₂O₇. Since there are 2 phosphorus atoms in the formula, we can calculate the total weight of phosphorus: \[ \text{Weight of phosphorus in Mg}_2\text{P}_2\text{O}_7 = 2 \times 31 = 62 \text{ g} \] ### Step 3: Calculate the Weight of Phosphorus in the Sample We have 2.5090 g of Mg₂P₂O₇. To find out how much phosphorus is in this amount, we set up a ratio: \[ \text{Weight of phosphorus in 2.5090 g of Mg}_2\text{P}_2\text{O}_7 = \left(\frac{62 \text{ g P}}{222 \text{ g Mg}_2\text{P}_2\text{O}_7}\right) \times 2.5090 \text{ g} \] Calculating this gives: \[ \text{Weight of phosphorus} = \left(\frac{62}{222}\right) \times 2.5090 \approx 0.173 \text{ g} \] ### Step 4: Calculate the Percentage of Phosphorus in the Organic Compound Now, we can calculate the percentage of phosphorus in the original organic compound: \[ \text{Percentage of phosphorus} = \left(\frac{\text{Weight of phosphorus}}{\text{Weight of organic compound}}\right) \times 100 \] Substituting the values: \[ \text{Percentage of phosphorus} = \left(\frac{0.173}{1.5}\right) \times 100 \approx 11.53\% \] ### Final Answer The percentage of phosphorus in the organic compound is approximately **11.53%**. ---
Promotional Banner

Topper's Solved these Questions

  • ESTIMATION OF ELEMENTS IN ORGANIC COMPOUNDS

    RC MUKHERJEE|Exercise Problems|13 Videos
  • EMPIRICAL, MOLECULAR AND STRUCTURAL FORMULAE

    RC MUKHERJEE|Exercise Problems|46 Videos
  • EUDIOMETRY OR GAS ANALYSIS

    RC MUKHERJEE|Exercise PROBLEMS |28 Videos

Similar Questions

Explore conceptually related problems

Estimation of phosphorous: Second method: A known mass of compound is heated with fuming HNO_(3) or sodium peroxide (Na_(2)O_(2) in Carius tube which converts phosphorous to H_(3)PO_(4) . Magnesia mixture (MgCl_(2)+NH_(4)Cl) is then added, which gives the percipate of magnesium ammonium phosphate (MgNH_(4).PO_(4)) which on heating gives magnesium pyrophosphate (Mg_(2)P_(2)O_(7)) , which is weighted. Percentage of P =("Atomic mass of P")/("Molecular mass of " Mg_(2)P_(2)O_(7)) xx ("Molecular mass of "Mg_(2)P_(2)O_(7) xx 100)/("Mass of compound")=(62)/(222) xx("Mass of " Mg_(2)P_(2)O_(7)xx 100)/("Mass of compound") 0.12 gm of and organic compound containing phosphorus gave 0.22 gm of Mg_(2)P_(2)O_(7) by the usual analysis. Calculate the percentage of phosphorus in the compound.

0.12 gm of an organic compound containing phosphorus gave 0.22 gm of Mg_2P_2O_7 by the usual analysis. Calculate the percentage of phosphorus in the compound.

0.40g of an organic compound containing phosphorus gave 0.555 g of Mg_(2)P_(2)O_(7) by usual analysis calculate the % of phosphorus in the organic compound