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448mL of a hydrocarbon (A) having C (87....

448mL of a hydrocarbon (A) having C (87.80%), H (12.19%) weight 1.64g at NTP. On hydrogenation it gives 2 methyl pentane. Treatment of (A) with acidic `HgSO_(4)` gives a new compound (B) of molecular weight `C_(6)H_(12)O`. Compound (A) does not react with ammoniacal `AgNO_(3)`. What is the structure of (A)?

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To determine the structure of the hydrocarbon (A), we will follow a systematic approach based on the information provided in the question. ### Step-by-Step Solution: 1. **Determine the Molar Mass of the Hydrocarbon (A)**: - Given: Volume of hydrocarbon (A) = 448 mL at NTP. - At NTP, 1 mole of gas occupies 22400 mL. - Number of moles of (A) = Volume / Molar Volume = 448 mL / 22400 mL/mol = 0.02 moles. ...
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RC MUKHERJEE-EMPIRICAL, MOLECULAR AND STRUCTURAL FORMULAE-Problems
  1. Compound (A) with molecular weight 108, contained 88.89%C and 11.11% H...

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  2. A compound 'X' containing C, H and O is unreactive towards sodium. It ...

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  3. 448mL of a hydrocarbon (A) having C (87.80%), H (12.19%) weight 1.64g ...

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  4. 0.369g of a bromo derivative of a hydrocarbon (A) when vaporised occup...

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  5. 0.90 gm of an organic compound C(4)H(10)O(2) (A) when treated with so...

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  6. An unknown compound of C, H and O contains 69.77% C and 11.63% H and h...

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  7. An organic compound (mol. Wt =44) (X) contains 54.54% of C and 9.09% o...

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  8. A ketone A, which undergoes halform reaction, gives compound B on redu...

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  9. An organic compound (A) having molecular weight, 58, contained 62.06% ...

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  10. An aromatic compound (X) contains C (79.25%) and H(5.66%). (X) on trea...

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  11. An aromatic compound (X) contained 58.5% of C, 4.1% of H and 11.4% of ...

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  12. An aliphatic amine (X) contains C (61.01%), H (15.25%) and N (23.74%)....

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  13. An organic compound (A) contains C=32%, H=6.66% and N=18.67%. On reduc...

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  14. Compound (A) gives positive Lucas test in 5 minutes. When 6g of (A) is...

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  15. An organic compound (A) of molecular weight 140.5 has 68.32%C, 6.4%H a...

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  16. 10g of mixture of hexane and ethanol is reated with Na to give 200 ml ...

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  17. A 0.535 gm mixture of ethanol and acetaldehyde when heated with Fehlin...

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  18. An organic compound, (A) containing C, H, N and O, on analysis gives 4...

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  19. A certain compound was known to have a formula which would be represen...

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  20. A gaseous hydrocarbon gives upon combustion 0.72g of water and 3.08g o...

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