Home
Class 12
CHEMISTRY
0.90 gm of an organic compound C(4)H(10)...

`0.90 gm` of an organic compound `C_(4)H_(10)O_(2) (A)` when treated with sodium gives `224 ml` of hydrogen at `NTP`. Compound (A) can be separated into fraction (B) and
(C ), by crystallisation of which the fraction (B) is resolved into isomers (D) and (E ). Write down the structural formula of (A) to (E ) with proper reasoning.

Text Solution

Verified by Experts

`[(CH_(3),CH_(3),CH_(3),),("|","|","|",),(H-C-OH,H-C-OH,OH-C-H,),("|","|","|",),(H-C-OH,OH-C-H,H-C-OH,),("|","|","|",),(CH_(3),CH_(3),CH_(3),),((C ),(D),(E),)]`
Promotional Banner

Topper's Solved these Questions

  • EMPIRICAL, MOLECULAR AND STRUCTURAL FORMULAE

    RC MUKHERJEE|Exercise Problems|46 Videos
  • ELEMENTARY PROBLEMS BASED ON DEFINITION OF MOLE: THE MOLE CONCEPT

    RC MUKHERJEE|Exercise OBJECTIVE PROBLEMS |29 Videos
  • ESTIMATION OF ELEMENTS IN ORGANIC COMPOUNDS

    RC MUKHERJEE|Exercise Problems|13 Videos

Similar Questions

Explore conceptually related problems

Two isomeric compounds, (A) and (B), have the same formula, C_(11)H_(13)OCI . Both are unsaturated, yield the same compound (C) on catalytic hydrogenation, and produce 4-chloro-3-ethoxybenzoic acid on vigorous oxidation. (A) exists in geometrical isomers, (D) and (E), but not (B). Give structures of (A) to (E) with proper reasoning.

0.44 gm of organic compound C_(x) H_(y) O which occupied 224 ml at NTP and on combustion gave 0.88 gm CO_(2) . The ratio of X to Y in the compound 1s

An organic compound (A) C_(5)H_(9) Br which readily decolourises bromine water and KMnO_(4) solution gives (B), C_(5)H_(11)Br on treatment with Sn//HCI . The reaction of (A) with NaNH_(2) produces (C) with evolution of ammonia (C) neither reacts with sodium nor forms any metal acetylide but reacts with Lindlar catalyst to give (D) and on reaction with Na//liq . NH_(3) produces (E) .Both the compounds (D) and (E) are isomeric. Give structures of (A) to (E) with proper reasoning.

An organic compound (A) of molecular formula C_(5)H_(8) when treated with Na in liquid ammonia followed by reaction with s-Propyl iodide yeidls (B) C_(8)H_(12) (A) gives a ketone C_(5)H_(10)O (e) when treated with dil H_(2)SO_(4) and HgSO_(4) (B) on oxidation with alkaline KMnO_(4) gives two isomeric acids (D) and (E) C_(4)H_(8)O_(2) . Give structures of compounds (A) to (E) with proper reasoning .

RC MUKHERJEE-EMPIRICAL, MOLECULAR AND STRUCTURAL FORMULAE-Problems
  1. A compound 'X' containing C, H and O is unreactive towards sodium. It ...

    Text Solution

    |

  2. 448mL of a hydrocarbon (A) having C (87.80%), H (12.19%) weight 1.64g ...

    Text Solution

    |

  3. 0.369g of a bromo derivative of a hydrocarbon (A) when vaporised occup...

    Text Solution

    |

  4. 0.90 gm of an organic compound C(4)H(10)O(2) (A) when treated with so...

    Text Solution

    |

  5. An unknown compound of C, H and O contains 69.77% C and 11.63% H and h...

    Text Solution

    |

  6. An organic compound (mol. Wt =44) (X) contains 54.54% of C and 9.09% o...

    Text Solution

    |

  7. A ketone A, which undergoes halform reaction, gives compound B on redu...

    Text Solution

    |

  8. An organic compound (A) having molecular weight, 58, contained 62.06% ...

    Text Solution

    |

  9. An aromatic compound (X) contains C (79.25%) and H(5.66%). (X) on trea...

    Text Solution

    |

  10. An aromatic compound (X) contained 58.5% of C, 4.1% of H and 11.4% of ...

    Text Solution

    |

  11. An aliphatic amine (X) contains C (61.01%), H (15.25%) and N (23.74%)....

    Text Solution

    |

  12. An organic compound (A) contains C=32%, H=6.66% and N=18.67%. On reduc...

    Text Solution

    |

  13. Compound (A) gives positive Lucas test in 5 minutes. When 6g of (A) is...

    Text Solution

    |

  14. An organic compound (A) of molecular weight 140.5 has 68.32%C, 6.4%H a...

    Text Solution

    |

  15. 10g of mixture of hexane and ethanol is reated with Na to give 200 ml ...

    Text Solution

    |

  16. A 0.535 gm mixture of ethanol and acetaldehyde when heated with Fehlin...

    Text Solution

    |

  17. An organic compound, (A) containing C, H, N and O, on analysis gives 4...

    Text Solution

    |

  18. A certain compound was known to have a formula which would be represen...

    Text Solution

    |

  19. A gaseous hydrocarbon gives upon combustion 0.72g of water and 3.08g o...

    Text Solution

    |

  20. The ration of mass per cent of C and H of an organic compound (C(x)H(y...

    Text Solution

    |