Home
Class 12
CHEMISTRY
A mixture of KMnO(4) and K(2)Cr(2)O(7) w...

A mixture of `KMnO_(4) and K_(2)Cr_(2)O_(7)` weighing `0.24` g on being treated with KI in acid solution liberates just sufficient `I_(2)` to react with 60 mL of `0.1` N `Ha_(2)S_(2)O_(3)` solution . Calculate percentage of Cr and Mn in the mixture .

Text Solution

Verified by Experts

The correct Answer is:
`20.83% , 14.17%`

`underset(+7) (KMnO_(4)) to underset(+2) (Mn^(2+))and underset(+12)(K_(2)Cr_(2)O_(7))to underset(+6)(2Cr^(3+)]`
Promotional Banner

Topper's Solved these Questions

  • VOLUMETRIC CALCULATIONS

    RC MUKHERJEE|Exercise OBJECTIVE PROBLEMS |37 Videos
  • VOLUMETRIC CALCULATIONS

    RC MUKHERJEE|Exercise OBJECTIVE PROBLEMS |37 Videos
  • SOLID AND LIQUID STATES

    RC MUKHERJEE|Exercise OBJECTIVE PROBLEMS |51 Videos

Similar Questions

Explore conceptually related problems

If equal volume of 1M KMnO_(4) and 1M K_(2)Cr_(2)O_(7) solution are used to react with Fe^(2+) oxidized will be :

Acidic K_(2) Cr_(2)O_(7) oxidises KI to

0.5 gmixture of K_(2)Cr_(2)O_(7) and KMnO_(4) was treated with excess of KI in acidic medium. Iodine liberated required 150 cm^(3) of 0.10 N solution of thiosulphate solution for titration. Find trhe percentage of K_(2)Cr_(2)O_(7) in the mixture :

A mixture of H_(2)C_(2)O_(4) and NaHC_(2)O_(4) weighing 2.02 g was dissolved in water and the solution made uptp one litre. 10 mL of this solution required 3.0 mL of 0.1 N NaOH solution for complete neutralization. In another experiment 10 mL of same solution in hot dilute H_(2)SO_(4) medium required 4 mL of 0.1N KMnO_(4) KMnO_(4) for compltete neutralization. Calculate the amount of H_(2)C_(2)O_(4) and NaHC_(2)O_(4) in mixture.

638.0 g of CuSO_(4) solution is titrated with excess of 0.2 M KI solution. The liberated I_(2) required 400 " mL of " 1.0 M Na_(2)S_(2)O_(3) for complete reaction. The percentage purity of CuSO_(4) in the sample is

RC MUKHERJEE-VOLUMETRIC CALCULATIONS -PROBLEMS
  1. Calculate the molarity og hudrogen chloride in a solution when 0.365 g...

    Text Solution

    |

  2. Derive a formula for the volume of water V(2) which must be added to V...

    Text Solution

    |

  3. Find out the equivalent weight of H(3) PO(4)in the reaction: Ca(OH)(...

    Text Solution

    |

  4. A 250-mL sample of 0.20 M hydrochloric acid to be made by diluting th...

    Text Solution

    |

  5. How many mL of each of two hydrochloric acids of strengths 12 N and 3 ...

    Text Solution

    |

  6. What volumes of 2 M and 6 M solutions of HCl have to be mixed to prepa...

    Text Solution

    |

  7. One litre of a solution contains 18 .9 g of HNO(3) and one litre of an...

    Text Solution

    |

  8. 10ml of sulphuric acid solution (sp.gr.=1.84) contains 98% weight of p...

    Text Solution

    |

  9. What is the molarity and molality of a 13 % solution ( by weight ) ...

    Text Solution

    |

  10. How many mL of concentrated suphuric acid of sp. Gr 1.84 containing 98...

    Text Solution

    |

  11. 26 mL of a 1 N NaCO(3) solution is neutralised by the acids A and B in...

    Text Solution

    |

  12. 25 mL of a solution of Fe^(2+) ions was titrated with a solution of ...

    Text Solution

    |

  13. Upon heating a litre of a N/2 HCl solution , 2.675 g of hydrogen chlo...

    Text Solution

    |

  14. 0.9546 g of a Rochelle salt , NaKC(4)H(4)O(6).4H(2)O on ignition ,gave...

    Text Solution

    |

  15. A mixture of KMnO(4) and K(2)Cr(2)O(7) weighing 0.24 g on being treate...

    Text Solution

    |

  16. Fedral regulations set an upper limit of 50 parts per millison (ppm) o...

    Text Solution

    |

  17. Fedral regulations set an upper limit of 50 parts per millison (ppm) o...

    Text Solution

    |

  18. Fedral regulations set an upper limit of 50 parts per millison (ppm) o...

    Text Solution

    |

  19. A compound H(2)X with molar weigth of 80g is dissolved in a solvent ha...

    Text Solution

    |

  20. To measure the quantity of MnCl(2) dissolved in an queous solution, it...

    Text Solution

    |