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100 mL of 0.5 N NaOH solution is added t...

100 mL of `0.5` N NaOH solution is added to 10 mL of 3 N `H_(2)SO_(4)` solution and 20 mL of 1 N HCl solution . The mixture is

A

acidic

B

alkaline

C

neutral

D

none of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the equivalents of the acids and bases involved in the reaction and see if they neutralize each other. ### Step-by-Step Solution: 1. **Calculate the equivalents of NaOH (base)**: - The formula for calculating equivalents is: \[ \text{Equivalents} = \text{Volume (L)} \times \text{Normality (N)} \] - For NaOH: - Volume = 100 mL = 0.1 L - Normality = 0.5 N - Therefore, the equivalents of NaOH: \[ \text{Equivalents of NaOH} = 0.1 \, \text{L} \times 0.5 \, \text{N} = 0.05 \, \text{equivalents} = 50 \, \text{meq} \] 2. **Calculate the equivalents of H₂SO₄ (acid)**: - For H₂SO₄: - Volume = 10 mL = 0.01 L - Normality = 3 N - Therefore, the equivalents of H₂SO₄: \[ \text{Equivalents of H₂SO₄} = 0.01 \, \text{L} \times 3 \, \text{N} = 0.03 \, \text{equivalents} = 30 \, \text{meq} \] 3. **Calculate the equivalents of HCl (acid)**: - For HCl: - Volume = 20 mL = 0.02 L - Normality = 1 N - Therefore, the equivalents of HCl: \[ \text{Equivalents of HCl} = 0.02 \, \text{L} \times 1 \, \text{N} = 0.02 \, \text{equivalents} = 20 \, \text{meq} \] 4. **Calculate the total equivalents of acids**: - Total equivalents of acids (H₂SO₄ + HCl): \[ \text{Total equivalents of acids} = 30 \, \text{meq} + 20 \, \text{meq} = 50 \, \text{meq} \] 5. **Compare the equivalents of acids and bases**: - Equivalents of NaOH (base) = 50 meq - Total equivalents of acids = 50 meq - Since the equivalents of acids and bases are equal, they will neutralize each other. 6. **Conclusion**: - The mixture is neutral because the equivalents of acid and base are equal. ### Final Answer: The mixture is neutral.
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