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The tendency to form p(pi) - p(pi) multi...

The tendency to form `p_(pi) - p_(pi)` multiple bonds in group 14 is
most prominent for

A

C

B

Si

C

Sn

D

Pb

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the tendency to form \( p_{\pi} - p_{\pi} \) multiple bonds in group 14 elements, we can follow these steps: ### Step 1: Understand the Group 14 Elements Group 14 of the periodic table consists of elements such as Carbon (C), Silicon (Si), Germanium (Ge), Tin (Sn), and Lead (Pb). ### Step 2: Identify the Concept of \( p_{\pi} - p_{\pi} \) Bonding The \( p_{\pi} - p_{\pi} \) bonding refers to the overlap of p-orbitals from adjacent atoms to form multiple bonds (like double or triple bonds). This type of bonding is crucial in determining the reactivity and bonding characteristics of the elements. ### Step 3: Analyze the Trend in Group 14 As we move down the group from Carbon to Lead: - The size of the atoms increases. - The effectiveness of \( p_{\pi} - p_{\pi} \) bonding decreases due to the larger atomic size and increased distance between the p-orbitals. - Additionally, larger atoms experience more repulsion between the electrons in the p-orbitals, which further reduces the tendency to form multiple bonds. ### Step 4: Compare the Elements - **Carbon**: Being the smallest element in the group, it has the highest tendency to form \( p_{\pi} - p_{\pi} \) multiple bonds with other elements (like nitrogen and oxygen). - **Silicon**: Although it can form some multiple bonds, its larger size and the associated factors reduce this tendency significantly. - **Germanium, Tin, and Lead**: These elements have even larger atomic sizes, making \( p_{\pi} - p_{\pi} \) bonding even less favorable. ### Step 5: Conclusion From the analysis, we conclude that the tendency to form \( p_{\pi} - p_{\pi} \) multiple bonds is most prominent for **Carbon** in Group 14. ### Final Answer The tendency to form \( p_{\pi} - p_{\pi} \) multiple bonds in group 14 is most prominent for **Carbon (C)**. ---

To solve the question regarding the tendency to form \( p_{\pi} - p_{\pi} \) multiple bonds in group 14 elements, we can follow these steps: ### Step 1: Understand the Group 14 Elements Group 14 of the periodic table consists of elements such as Carbon (C), Silicon (Si), Germanium (Ge), Tin (Sn), and Lead (Pb). ### Step 2: Identify the Concept of \( p_{\pi} - p_{\pi} \) Bonding The \( p_{\pi} - p_{\pi} \) bonding refers to the overlap of p-orbitals from adjacent atoms to form multiple bonds (like double or triple bonds). This type of bonding is crucial in determining the reactivity and bonding characteristics of the elements. ...
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