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The + l-effect of alkyl groups is in the...

The + l-effect of alkyl groups is in the order ........` gt 2^@ gt `........

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`3^@ ,1^@`
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Fill in the blanks by choosing the appropriate word/words from those given in the brackets: [proton acceptor, pressures, non-spontaneous, proton donor, spontaneous, 3°, brown, red, 1°, temperatures, copper acetylide] (i) According to Bronsted and Lowry, an acid is a_______ (ii) When DeltaH is a negative and T Delta S is a positive, the process is______ (iii) The +I effect of alkyl groups is in the order ______ gt 2^(@) gt ________ (iv) When acetylene is treated with ammoniacal cuprous chloride a _____ precipitate of _____ is formed.

The reactivity of carbanions follows the order 3^@ gt 2^@ gt 1^@ .

Assertion( A) The boiling points of alkyl halides decrease in the order RI gt RBr gt RCl gt RF Reason (R) The boiling points of alkyl chlorides, bromides and iodides are considerably higher than that of the hydrocarbon of comparable molecular mass.

Statement-I: Boiling point of alkyl halide increases with increases in molecular weight. Because Statement-II: Boiling point of alkyhalides are in the order RI gt RBr gt RCI gt RF .

2x - y gt 1, 2y - x gt 1

Alkyl halides are formed when thionyl chloride and _____ are refluxed in presence of pyridine. The order of reactivity (3^(@)gt2^(@)gt1^(@)) is due to +1 effect of the alkyl group which____ the polarity of C-X bond.

The solubility product of CuS, Ag2S and HgS are 10^(-31),10^(-44),10^(-54) respectively. The solubility of these sulphides are in the order (a) Ag2S gt HgS gt CuS (b) HgS gt CdS gt CuS (c) Ag2S gt CuS gt HgS (d) CuS gt CdS gt HgS

In group 14 of the periodic table, the oxidising power of tetravalent species decreases in the order a. Ge gt Pb gt Sn b. Ge gt Sn gt Pb c. Pb gt Ge gt Sn d. Pb gt Sn gt Ge

Assertion Boiling point of halogen acids are in the order HF gtHBr gt HCl gt HI Reasoning Electronegativities are in the order F gt Cl gt Br gt I .

Why is +l-effect of t-butyl group greater than that of isopropyl group?

ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -FILL IN THE BLANK TYPE QUESTIONS
  1. When an organic compound contains a halogen along with N and S, haloge...

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  2. The yellow precipitate obtained in the detection of phosphorus is .......

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  3. In the estimation of nitrogen by Kjeldahl's method, the compound is he...

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  4. In the estimation of sulphur by Carius method, sulphur is oxidised to ...

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  5. Victor Meyer's method makes use of the fact that ............ gram mol...

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  6. Molecular mass of an acid = Equivalent mass x ......

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  7. Inductive effect involves

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  8. The + l-effect of alkyl groups is in the order ........ gt 2^@ gt ....

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  9. Electromeric effect is a .......... effect and involves transfer of .....

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  10. Among -OH and gt C=0 , the group causing + M-effect is .......... gro...

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  11. Why is a 3 free radical more stable as compared to 1^@ and 2^@ free r...

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  12. The central carbon in a carbocation is .......... hybridised.

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  13. What are carbocations ? Discuss their orbital structure and explain th...

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  14. In a singlet carbene, the lone pair of electrons is present in a ........

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  15. Free radicals and carbenes act as .......... philic reagents.

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  16. Nucleophiles are Lewis .......... and possess .......... pair of elect...

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  17. What is molarity?

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  18. What is the optical nature of the product obtained in an S(N^1) reacti...

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  19. The Friedel-Crafts methylation of benzene involves ..........

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  20. Addition of bromine to ethylene is .......... addition reaction.

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