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In the following reaction, 'X' refers to...

In the following reaction, 'X' refers to the compound:
`HCHO+CH_(3)MgI underset("ether")overset("dry")to "Intermediate" underset(H^(+)//H_(2)O) overset(HCl)to 'X'`

A

`CH_(3)OH`

B

`CH_(3)CH_(2)OH`

C

`CH_(3)COCH_(3)`

D

`CH_(3)OCH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the given reaction step by step. ### Step 1: Identify the Reactants The reaction involves formaldehyde (HCHO) and a Grignard reagent, which is methylmagnesium iodide (CH3MgI). The solvent used is dry ether. ### Step 2: Understand the Grignard Reaction Grignard reagents react with carbonyl compounds (like aldehydes and ketones) to form alcohols. In this case, HCHO (formaldehyde) will react with CH3MgI. ### Step 3: Reaction Mechanism 1. The carbon atom in HCHO is electrophilic due to the presence of the carbonyl group (C=O). 2. The nucleophilic carbon from the Grignard reagent (CH3-) attacks the electrophilic carbon in HCHO. 3. This forms a tetrahedral intermediate where the oxygen atom of the carbonyl group becomes negatively charged (alkoxide ion). ### Step 4: Formation of the Intermediate The reaction can be represented as: \[ \text{HCHO} + \text{CH}_3\text{MgI} \rightarrow \text{H}_2\text{C(OH)(CH}_3)\text{MgI} \] This intermediate has a structure where: - The carbon is now bonded to a hydroxyl group (-OH) and a methyl group (-CH3). ### Step 5: Hydrolysis of the Intermediate Next, we treat this intermediate with H+ and H2O (acidic hydrolysis): 1. The alkoxide ion (O-) will react with water. 2. The magnesium iodide bond will break, and the oxygen will get protonated (H+ from HCl). 3. This results in the formation of an alcohol. ### Step 6: Identify the Product The final product after hydrolysis will be: \[ \text{CH}_3\text{CH}_2\text{OH} \] This compound is ethanol. ### Conclusion The compound 'X' formed in the reaction is ethanol (CH3CH2OH). ### Answer Thus, the answer is: **X = CH3CH2OH (Ethanol)**

To solve the question, we need to analyze the given reaction step by step. ### Step 1: Identify the Reactants The reaction involves formaldehyde (HCHO) and a Grignard reagent, which is methylmagnesium iodide (CH3MgI). The solvent used is dry ether. ### Step 2: Understand the Grignard Reaction Grignard reagents react with carbonyl compounds (like aldehydes and ketones) to form alcohols. In this case, HCHO (formaldehyde) will react with CH3MgI. ...
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Knowledge Check

  • Consider the following reaction sequence , CH_(3)CH(OH)CH_(3) overset("Conc" H_(2)SO_(4))underset("Heat")(to) X underset(H_(2)O) overset("dil." H_(2)SO_(4))(to) Y X and Y in the reaction respectively are

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    B
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    C
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    B
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