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To prepare 2-propanol from methylmagnesi...

To prepare 2-propanol from methylmagnesium bromide, the other chemical required is

A

HCHO

B

`CH_(3)CHO`

C

`C_(2)H_(5)OH`

D

`O=C=O`

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The correct Answer is:
To prepare 2-propanol from methylmagnesium bromide (CH3MgBr), we need to identify the appropriate reactant from the given options. The options provided are: A) HCHO (formaldehyde) B) CH3CHO (acetaldehyde) C) C2H5OH (ethanol) D) CO2 (carbon dioxide) ### Step-by-Step Solution: 1. **Understanding the Grignard Reagent**: Methylmagnesium bromide (CH3MgBr) is a Grignard reagent. Grignard reagents react with carbonyl compounds to form alcohols after hydrolysis. 2. **Identifying the Target Product**: The target product is 2-propanol, which has the structure CH3-CHOH-CH3. This molecule contains three carbon atoms. 3. **Analyzing the Carbon Count**: Since we need to form a product with three carbon atoms (2-propanol), the reactant must provide at least two additional carbon atoms when reacting with the one carbon from CH3MgBr. 4. **Evaluating Each Option**: - **Option A: HCHO (formaldehyde)** - Contains 1 carbon atom. - Reaction: CH3MgBr + HCHO → CH3-CH2OH (1 carbon from HCHO + 1 from CH3MgBr = 2 carbons). - Not suitable as it cannot form 2-propanol. - **Option B: CH3CHO (acetaldehyde)** - Contains 2 carbon atoms. - Reaction: CH3MgBr + CH3CHO → CH3-CH(OH)-CH3 (2 carbons from CH3CHO + 1 from CH3MgBr = 3 carbons). - This reaction can yield 2-propanol, making it a suitable option. - **Option C: C2H5OH (ethanol)** - Contains 2 carbon atoms. - Reaction: CH3MgBr + C2H5OH does not yield a suitable electrophilic carbon for the Grignard reagent to attack, so it will not form 2-propanol. - **Option D: CO2 (carbon dioxide)** - Contains 1 carbon atom. - Reaction: CH3MgBr + CO2 → CH3COOMgBr, which upon hydrolysis gives CH3COOH (acetic acid), not 2-propanol. 5. **Conclusion**: The only reactant that can yield 2-propanol when reacted with methylmagnesium bromide is **option B: CH3CHO (acetaldehyde)**. ### Final Answer: **The other chemical required is CH3CHO (acetaldehyde).**
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ICSE-ALCOHOLS, PHENOLS AND ETHERS -EXERCISE (PART-I Objective Questions) (Choose the correct alternative)
  1. Order of reactivity of alcohols towards sodium metal is

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  2. In the following reaction, 'X' refers to the compound: HCHO+CH(3)MgI...

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  3. To prepare 2-propanol from methylmagnesium bromide, the other chemica...

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  4. n-propyl alcohol and isopropyl alcohol are examples of

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  5. Compound 'A' with the formula C(3)H(8)O on vigorous oxidation produce...

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  6. When ethyl hydrogensulphate is heated at 140^(@)C with excess of alco...

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  7. The compound that reacts fastest with Lucas reagent at room temperatu...

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  8. The reaction of Lucas reagent is fast with

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  9. Which of the following reaction conditions is used for the conversion...

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  10. Monochlorination of toluene in sunlight followed by hydroysis with aq....

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  11. How many alcohos with molecular formula C4H10O are chiral in nature?

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  12. What is the correct order of reactivity of alcohols in the following r...

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  13. CH(3)CH(2)OH can be converted into CH(3)CHO by........... .

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  14. The process of converting alkyl halids into alcohols involves

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  15. Which of the following compounds is aromatic alcohol ?

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  16. Give IUPAC name of the compound given below. CH(3)-underset(Cl)under...

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  17. IUPAC name of m-cresol is.......... .

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  18. IUPAC name of the compound CH(3)-underset(CH(3))underset(|)(CH)-OCH(3)...

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  19. Which of the following species can act as the strongest base ?

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  20. Which of the following compounds will react with sodium hydroxide solu...

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