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When ethyl hydrogensulphate is heated at...

When ethyl hydrogensulphate is heated at `140^(@)C` with excess of alcohol, the product formed is

A

ethane

B

ethylene

C

diethyl ether

D

diethyl sulfate

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The correct Answer is:
To solve the question of what product is formed when ethyl hydrogen sulfate is heated with excess alcohol at 140°C, we can follow these steps: ### Step 1: Identify the Reactants The reactant in this case is ethyl hydrogen sulfate, which has the chemical formula C2H5HSO4. We are also using excess alcohol, which we can assume to be ethanol (C2H5OH) for this reaction. ### Step 2: Understand the Reaction Conditions The reaction is taking place at a temperature of 140°C. This temperature is significant as it can facilitate the reaction between ethyl hydrogen sulfate and the alcohol. ### Step 3: Predict the Reaction Type The reaction between an alcohol and an alkyl hydrogen sulfate typically leads to the formation of an ether. In this case, we are looking at the formation of diethyl ether. The mechanism of this reaction is an SN2 mechanism, which involves the nucleophilic substitution of the alcohol on the alkyl hydrogen sulfate. ### Step 4: Write the Reaction Equation When ethyl hydrogen sulfate reacts with ethanol, the following reaction occurs: \[ \text{C2H5HSO4} + \text{C2H5OH} \rightarrow \text{C2H5OC2H5} + \text{H2SO4} \] This shows that diethyl ether (C2H5OC2H5) and sulfuric acid (H2SO4) are formed. ### Step 5: Identify the Product From the reaction, we can see that the main product formed is diethyl ether (C2H5OC2H5). ### Conclusion Thus, the product formed when ethyl hydrogen sulfate is heated at 140°C with excess alcohol is **diethyl ether**. ### Final Answer The correct option is **C. diethyl ether**. ---

To solve the question of what product is formed when ethyl hydrogen sulfate is heated with excess alcohol at 140°C, we can follow these steps: ### Step 1: Identify the Reactants The reactant in this case is ethyl hydrogen sulfate, which has the chemical formula C2H5HSO4. We are also using excess alcohol, which we can assume to be ethanol (C2H5OH) for this reaction. ### Step 2: Understand the Reaction Conditions The reaction is taking place at a temperature of 140°C. This temperature is significant as it can facilitate the reaction between ethyl hydrogen sulfate and the alcohol. ...
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ICSE-ALCOHOLS, PHENOLS AND ETHERS -EXERCISE (PART-I Objective Questions) (Choose the correct alternative)
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  2. Compound 'A' with the formula C(3)H(8)O on vigorous oxidation produce...

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  3. When ethyl hydrogensulphate is heated at 140^(@)C with excess of alco...

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  4. The compound that reacts fastest with Lucas reagent at room temperatu...

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  5. The reaction of Lucas reagent is fast with

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  6. Which of the following reaction conditions is used for the conversion...

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  7. Monochlorination of toluene in sunlight followed by hydroysis with aq....

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  8. How many alcohos with molecular formula C4H10O are chiral in nature?

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  9. What is the correct order of reactivity of alcohols in the following r...

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  10. CH(3)CH(2)OH can be converted into CH(3)CHO by........... .

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  11. The process of converting alkyl halids into alcohols involves

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  12. Which of the following compounds is aromatic alcohol ?

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  13. Give IUPAC name of the compound given below. CH(3)-underset(Cl)under...

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  14. IUPAC name of m-cresol is.......... .

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  15. IUPAC name of the compound CH(3)-underset(CH(3))underset(|)(CH)-OCH(3)...

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  16. Which of the following species can act as the strongest base ?

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  17. Which of the following compounds will react with sodium hydroxide solu...

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  18. Phenol is less acidic than

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  19. Which of the following is most acidic ?

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  20. Mark the correct order of decreasing acid strength of the following co...

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