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When diethyl ether is heated with conc. ...

When diethyl ether is heated with conc. sulfuric acid under pressure, it forms

A

Propanoic acid

B

Acetic acid

C

Ethyl alcohol

D

Acetic acid

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The correct Answer is:
To solve the question of what happens when diethyl ether is heated with concentrated sulfuric acid under pressure, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are diethyl ether (C2H5-O-C2H5) and concentrated sulfuric acid (H2SO4). 2. **Understand the Reaction Conditions**: - The reaction is conducted under heat and pressure, which can facilitate the breaking of bonds in the ether. 3. **Break Down the Ether**: - Diethyl ether can be represented as C2H5-O-C2H5. When it reacts with concentrated sulfuric acid, the ether bond (C-O) can be broken. 4. **Protonation of Ether**: - The sulfuric acid dissociates into H+ and HSO4-. The H+ ion can protonate the ether oxygen, making it more susceptible to nucleophilic attack. 5. **Formation of Ethanol**: - The protonated ether can undergo cleavage, leading to the formation of ethyl alcohol (C2H5OH) and an ethyl sulfate (C2H5HSO4) as a side product. 6. **Final Products**: - The main product formed from this reaction is ethyl alcohol (ethanol), and the side product is ethyl hydrogen sulfate (C2H5HSO4). 7. **Conclusion**: - Therefore, when diethyl ether is heated with concentrated sulfuric acid under pressure, the primary product formed is ethyl alcohol. ### Final Answer: - The product formed is **ethyl alcohol (ethanol)**. ---

To solve the question of what happens when diethyl ether is heated with concentrated sulfuric acid under pressure, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are diethyl ether (C2H5-O-C2H5) and concentrated sulfuric acid (H2SO4). 2. **Understand the Reaction Conditions**: ...
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ICSE-ALCOHOLS, PHENOLS AND ETHERS -EXERCISE (PART-I Objective Questions) (Choose the correct alternative)
  1. The reaction C(2)H(5)ONa +C(2)H(5)I to C(2)H(5)OC(2)H(5)+Nal is called

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  2. Diethyl ether on heating with excess of HI yields

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  3. When diethyl ether is heated with conc. sulfuric acid under pressure,...

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  4. When vapours of ethyl alcohol are passed over Al(2)O(3) at 250^(@)C,...

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  5. Tert. butyl chloride on treatment with sodium alkoxide yields

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  6. Diethyl ether on treatment with Cl(2) in presence of sunlight gives

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  7. Complete combustion of ether gives?

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  8. Which of the following pairs of reagents will not form ether?

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  9. According to Lewis concept of acids and bases, ethers are

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  10. Oxygen atom of ether is

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  11. Williamson synthesis is used to prepare

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  12. Sometimes explosion may occur while distilling ether. It may be due t...

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  13. Diethyl ether is soluble in

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  14. Ethoxyethane does not react with

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  15. Which of the following statement is correct?

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  16. Intermolecular hydrogen bonds are not present in ?

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  17. When methyl iodide is heated with sodium ethoxide, it forms?

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  18. Diethyl ether can be decomposed with

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  19. Diethyl ether absorbs oxygen to form

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  20. Ethers in contact with air for a long time form peroxides. The presen...

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