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Consider the following two molecules and...

Consider the following two molecules and according to the given information select correct statement(s) about `AX_(2) and AY_(2)` :
where A: 16th group of 3rd period element
X: more electronegative than (A) and same group number of (A) ltbgt Y: Less atomic size than (A) and same period number of (A)

A

The hybridization of central atoms are different in both compounds

B

The shape of both molecules are same

C

Both compounds are planar

D

The X-A-X bond angle is less than Y-A-Y bond angle

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem regarding the molecules AX₂ and AY₂, we will follow these steps: ### Step 1: Identify the elements A, X, and Y - A is a 16th group element from the 3rd period. The only element that fits this description is **Sulfur (S)**. - X is more electronegative than A and in the same group as A. The element that fits this description is **Oxygen (O)**, which is above sulfur in group 16. - Y is less in atomic size than A and in the same period as A. The element that fits this description is **Chlorine (Cl)**, which is in the same period (3rd period) but to the right of sulfur. ### Step 2: Write the chemical formulas for AX₂ and AY₂ - The compound AX₂ is **SO₂** (sulfur dioxide). - The compound AY₂ is **SCl₂** (sulfur dichloride). ### Step 3: Determine the hybridization of the central atom in both compounds - For SO₂, sulfur has a hybridization of **sp²** because it forms two double bonds (with oxygen) and has one lone pair. - For SCl₂, sulfur has a hybridization of **sp³** because it forms two single bonds (with chlorine) and has two lone pairs. ### Step 4: Analyze the shape of both molecules - The shape of SO₂ is **bent** due to the presence of one lone pair and the two bonded pairs. - The shape of SCl₂ is also **bent** due to the presence of two lone pairs and two bonded pairs. ### Step 5: Compare the bond angles in both compounds - In SO₂, the bond angle (O-S-O) is approximately **120°** due to the sp² hybridization. - In SCl₂, the bond angle (Cl-S-Cl) is less than **109.5°** due to the sp³ hybridization and the presence of lone pairs. ### Step 6: Evaluate the correctness of the statements 1. **The hybridization of the central atom is different in both compounds.** - **Correct** (SO₂ is sp², SCl₂ is sp³). 2. **The shape of both molecules is the same.** - **Correct** (Both are bent). 3. **The bond angle XAX is less than XAY.** - **Incorrect** (The bond angle in SO₂ is greater than in SCl₂). ### Conclusion The correct statements about AX₂ and AY₂ are: - The hybridization of the central atom is different in both compounds. - The shape of both molecules is the same.

To solve the problem regarding the molecules AX₂ and AY₂, we will follow these steps: ### Step 1: Identify the elements A, X, and Y - A is a 16th group element from the 3rd period. The only element that fits this description is **Sulfur (S)**. - X is more electronegative than A and in the same group as A. The element that fits this description is **Oxygen (O)**, which is above sulfur in group 16. - Y is less in atomic size than A and in the same period as A. The element that fits this description is **Chlorine (Cl)**, which is in the same period (3rd period) but to the right of sulfur. ### Step 2: Write the chemical formulas for AX₂ and AY₂ ...
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  11. Select correct statement(s) regarding sigma and pi bonds :

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