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The correct order of the strength of H-b...

The correct order of the strength of H-bonds is :

A

`H….FgtH….OgtH…..N`

B

`H….NgtH….OgtH….F`

C

`H….OgtH….NgtH….F`

D

`H….FgtH….NgtH….O`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of the strength of hydrogen bonds, we can follow these steps: ### Step 1: Understand Hydrogen Bonding Hydrogen bonding occurs when hydrogen is covalently bonded to a highly electronegative atom (like F, O, or N) and interacts with another electronegative atom. The strength of hydrogen bonds is influenced by the electronegativity of the atoms involved. **Hint:** Recall that electronegativity is the tendency of an atom to attract electrons. The more electronegative the atom bonded to hydrogen, the stronger the hydrogen bond. ### Step 2: Identify the Atoms Involved In the question, we are considering hydrogen bonds involving three different atoms: fluorine (F), oxygen (O), and nitrogen (N). **Hint:** Make a list of the atoms and their electronegativities to compare them. ### Step 3: Compare Electronegativity The electronegativity values for the relevant atoms are approximately: - Fluorine (F): 4.0 - Oxygen (O): 3.5 - Nitrogen (N): 3.0 From this, we can see that fluorine is the most electronegative, followed by oxygen, and then nitrogen. **Hint:** Remember that the greater the difference in electronegativity between hydrogen and the electronegative atom, the stronger the hydrogen bond. ### Step 4: Determine the Strength of Hydrogen Bonds Based on the electronegativity values, we can predict the strength of the hydrogen bonds: - HF (Hydrogen Fluoride) will have the strongest hydrogen bond due to fluorine's high electronegativity. - HO (Water) will have a weaker hydrogen bond than HF but stronger than HN. - HN (Hydrogen Nitride or Ammonia) will have the weakest hydrogen bond among these three. **Hint:** Think about how the strength of hydrogen bonds decreases with decreasing electronegativity of the atom bonded to hydrogen. ### Step 5: Write the Order of Strength Thus, the order of strength of hydrogen bonds from strongest to weakest is: 1. HF (Hydrogen Fluoride) 2. HO (Water) 3. HN (Ammonia) **Hint:** You can visualize this order as a ranking system based on electronegativity. ### Final Answer The correct order of the strength of hydrogen bonds is: **HF > HO > HN**.
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VK JAISWAL ENGLISH-CHEMICAL BONDING (ADVANCED)-SUBJECTIVE PROBLEMS
  1. The correct order of the strength of H-bonds is :

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  2. There are two groups of compounds A and B. Groups A contains three com...

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  3. Consider the following three compounds (i)AX(2n)^(n-), (ii)AX(3n) and...

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  4. When B(2)H(4) is allowed to react with following lewis bases, then how...

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  5. Consider the following elements A, B, C and D and their outer electron...

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  6. Consider following four compounds: (i) C(x) O(y) (ii) C(x)O(y+1) ...

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  7. Calculate expression (x+y+z) for diatomic molecules. where x=Total n...

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  8. If Hund rule violate, then find the total number of species among foll...

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  9. Consider the following table Than calculate value of experssion...

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  10. Total number of species among following, in which bond angle is equal...

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  11. Total number of unpaired electrons(s) present in both cationic and an...

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  12. Total number of species which has/ have symmetrical electronic distrib...

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  13. Total number of molecules, in which each covalent bond is comprised of...

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  14. Total number of angle in SeCl(4) which are less than 90^(@).

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  15. Consider the following species O(Me)(2), N(SiH(3))(3), CO, O(SiH(3))(2...

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  16. Total number of molecules which can form H-bond among themselves. Si...

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  17. Consider two covalent compounds AL(n(1)) and BL(n(2)), if central atom...

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  18. Calculate the I-I distance in (Å) for given compound H(2)C(2) I(2) if ...

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  19. There are some arrangements of atomic orbitals which are given below: ...

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  20. Number of hybrid orbital C atoms which have 33% p-character in C(CN)(4...

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  21. Max. no. of equal P-O bonds in P(2)O(7)^(4-) ion is :

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