Home
Class 12
CHEMISTRY
The comcept of redistribution of energy ...

The comcept of redistribution of energy in different orbitals of an atom associated with different energies to give new orbitals of equal (or somethimes it may be non-equal) energy oriented in space in definite directions is called hybridization and formed new orbitals are called hybrid orbitals. The bonds formed by such orbitals are called hybrid bonds. The process of mixing of orbitals itself requires some energy. Thus, some additional energy, is needed for the hybridisation (mixing) of atomic orbitals.
Q. Which of the following statement is correct?

A

In `BrF_(3)`, maximum three halogen atoms can lie in same plane

B

In `CH_(2)SF_(2)(CH_(3))_(2)` molecule all hydrogen atoms which bonded to `s-sp^(2)`overlapping, lie in equitorial plane

C

In `OSCl_(4), Cl-S-Cl` equitorial bond angle is greater than `120^(@)`

D

Molecules `IOF_(5) and XeO_(2)F_(4)` have similar shape but have different number of lone pairs in whole molecule

Text Solution

Verified by Experts

The correct Answer is:
B

(a) `implies ` Maximum number of atoms that can lie in a plane =4
(b) `implies` Hydrogen atoms bonded by `1s-sp^(2)` overlapping lie in axial
(c) `impliesangleCl-S-Cl` is less than `120^(@) ` due to shifting of s-character in S=O bond. (d)
No. of lone pairs =17 : No.of lone pairs=16
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING (ADVANCED)

    VK JAISWAL ENGLISH|Exercise ONE OR MORE ANSWER IS/ARE CORRECT|78 Videos
  • CHEMICAL BONDING (ADVANCED)

    VK JAISWAL ENGLISH|Exercise MATCH THE COLUMN|21 Videos
  • CHEMICAL BONDING (ADVANCED)

    VK JAISWAL ENGLISH|Exercise Level 2|150 Videos
  • CHEMICAL BONDING (BASIC)

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|54 Videos
VK JAISWAL ENGLISH-CHEMICAL BONDING (ADVANCED)-Level 3
  1. In all expected compounds each central atom only uses its s and p-orbi...

    Text Solution

    |

  2. The comcept of redistribution of energy in different orbitals of an at...

    Text Solution

    |

  3. The comcept of redistribution of energy in different orbitals of an at...

    Text Solution

    |

  4. The comcept of redistribution of energy in different orbitals of an at...

    Text Solution

    |

  5. Drago suggested an emprical rule which is compatible with the energeti...

    Text Solution

    |

  6. Drago suggested an emprical rule which is compatible with the energeti...

    Text Solution

    |

  7. According to hybridisation theory, the % s-character in sp, sp^(2) and...

    Text Solution

    |

  8. According to hybridisation theory, the % s-character in sp, sp^(2) and...

    Text Solution

    |

  9. The correct statement is :

    Text Solution

    |

  10. PCl(5) is an example of a molecule having sp^(3)d-hybridisation. Three...

    Text Solution

    |

  11. PCl(5) is an example of a molecule having sp^(3)d-hybridisation. Three...

    Text Solution

    |

  12. The first compound of the noble gasees was made in 1962. Barlett and L...

    Text Solution

    |

  13. The first compound of the noble gasees was made in 1962. Barlett and L...

    Text Solution

    |

  14. The first compound of the noble gasees was made in 1962. Barlett and L...

    Text Solution

    |

  15. According to MOT, two atomic orbitals overlap resulting in the formati...

    Text Solution

    |

  16. According to MOT, two atomic orbitals overlap resulting in the formati...

    Text Solution

    |

  17. According to MOT, two atomic orbitals overlap resulting in the formati...

    Text Solution

    |

  18. According to MOT, two atomic orbitals overlap resulting in the formati...

    Text Solution

    |

  19. According to MOT, two atomic orbitals overlap resulting in the formati...

    Text Solution

    |

  20. According to MOT, two atomic orbitals overlap resulting in the formati...

    Text Solution

    |