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Correct statement (s) regarding As(CH(3)...

Correct statement (s) regarding `As(CH_(3))F_(2)Cl_(2)` molecule is/are:

A

Maximum three halogen atoms can lie in same plane

B

Both axial and equatorial plane may have equal number of atoms

C

`As-Cl` bond length is longer than `As-F` bond length .

D

Maximum five atoms can lie in equatorial plane.

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The correct Answer is:
To analyze the molecule As(CH₃)F₂Cl₂ and determine the correctness of the statements regarding it, we will follow these steps: ### Step 1: Determine the Valence Electrons Arsenic (As) has 5 valence electrons. The other atoms contribute as follows: - Carbon (C) in CH₃ contributes 4 electrons (1 for each H and 3 for C). - Each Fluorine (F) contributes 1 electron (2 total for F₂). - Each Chlorine (Cl) contributes 1 electron (2 total for Cl₂). Total valence electrons = 5 (As) + 4 (C) + 2 (F) + 2 (Cl) = 13 valence electrons. ### Step 2: Draw the Lewis Structure 1. Place As at the center. 2. Attach the CH₃ group, two F atoms, and two Cl atoms around As. 3. The arrangement will be trigonal bipyramidal, with the CH₃ group in the equatorial position. ### Step 3: Analyze the Statements 1. **Statement 1**: Maximum 3 halogen atoms can lie in the same plane. - **Analysis**: In the trigonal bipyramidal structure, the equatorial plane can accommodate 3 atoms. Therefore, this statement is **true**. 2. **Statement 2**: Both axial and equatorial planes may have equal numbers of atoms. - **Analysis**: The equatorial plane has 3 atoms (2 Cl and 1 CH₃) and the axial plane has 2 atoms (2 F). Thus, this statement is **false**. 3. **Statement 3**: As-Cl bond length is longer than As-F bond length. - **Analysis**: Chlorine is larger than fluorine, leading to a longer bond length for As-Cl compared to As-F. Therefore, this statement is **true**. 4. **Statement 4**: Maximum 5 atoms can lie in the equatorial plane. - **Analysis**: In the equatorial plane, we can only fit 3 atoms (2 Cl and 1 CH₃) due to the geometry. Therefore, this statement is **false**. ### Conclusion The correct statements regarding the As(CH₃)F₂Cl₂ molecule are: - Statement 1: True - Statement 2: False - Statement 3: True - Statement 4: False Thus, the correct statements are 1 and 3. ---

To analyze the molecule As(CH₃)F₂Cl₂ and determine the correctness of the statements regarding it, we will follow these steps: ### Step 1: Determine the Valence Electrons Arsenic (As) has 5 valence electrons. The other atoms contribute as follows: - Carbon (C) in CH₃ contributes 4 electrons (1 for each H and 3 for C). - Each Fluorine (F) contributes 1 electron (2 total for F₂). - Each Chlorine (Cl) contributes 1 electron (2 total for Cl₂). ...
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