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Select the correct statement(s) about th...

Select the correct statement(s) about the compound `NO[BF_(4)]:`

A

It has `5sigma and 2pi` bond

B

Nitrogen-oxygen bond length is higher than nitric oxide `(NO)`

C

It is a diamagnetic species

D

`B-F` bond length in this compound is lower than in `BF_(3)`

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The correct Answer is:
To solve the question regarding the compound \( NO[BF_4] \), we will analyze the statements provided and determine their correctness based on the molecular structure and bonding characteristics of the compound. ### Step-by-Step Solution: 1. **Identify the Structure of \( NO[BF_4] \)**: - The compound can be represented as \( NO^+ \) (nitric oxide cation) and \( BF_4^- \) (tetrafluoroborate anion). - The structure consists of a nitrogen-oxygen bond in the cation and a boron atom surrounded by four fluorine atoms in the anion. 2. **Calculate the Bond Order of \( NO^+ \)**: - The Lewis structure of \( NO^+ \) shows a nitrogen-oxygen bond with one sigma bond and two pi bonds. - The bond order is calculated as follows: \[ \text{Bond Order} = \frac{\text{Total number of bonds}}{\text{Number of sigma bonds}} = \frac{3}{1} = 3 \] 3. **Calculate the Bond Order of \( NO \)**: - For \( NO \), the bond order is found to be 2.5, indicating that the bond length in \( NO \) is greater than that in \( NO^+ \). 4. **Analyze the Sigma and Pi Bonds in \( NO[BF_4] \)**: - In \( NO[BF_4] \), we have: - From \( NO^+ \): 1 sigma bond. - From \( BF_4^- \): 4 sigma bonds (one for each \( B-F \) bond). - Total sigma bonds = 1 (from \( NO^+ \)) + 4 (from \( BF_4^- \)) = 5 sigma bonds. - Total pi bonds = 2 (from \( NO^+ \)). - Therefore, the total bond count is 5 sigma and 2 pi bonds. 5. **Evaluate Each Statement**: - **Statement A**: "It has five sigma and two pi bonds." - **Correct**: As calculated, there are indeed 5 sigma and 2 pi bonds. - **Statement B**: "Nitrogen-oxygen bond length is higher than that in nitric oxide." - **Incorrect**: Since the bond order of \( NO^+ \) is greater than that of \( NO \), the bond length of \( NO^+ \) is less than that of \( NO \). - **Statement C**: "It is a diamagnetic species." - **Correct**: Both \( NO^+ \) and \( BF_4^- \) are diamagnetic, making the entire compound diamagnetic. - **Statement D**: "BF bond length in this compound is lower than that in \( BF_3 \)." - **Incorrect**: The presence of back-bonding in \( BF_3 \) results in shorter \( B-F \) bond lengths compared to those in \( BF_4^- \). ### Conclusion: The correct statements about the compound \( NO[BF_4] \) are **A** and **C**.

To solve the question regarding the compound \( NO[BF_4] \), we will analyze the statements provided and determine their correctness based on the molecular structure and bonding characteristics of the compound. ### Step-by-Step Solution: 1. **Identify the Structure of \( NO[BF_4] \)**: - The compound can be represented as \( NO^+ \) (nitric oxide cation) and \( BF_4^- \) (tetrafluoroborate anion). - The structure consists of a nitrogen-oxygen bond in the cation and a boron atom surrounded by four fluorine atoms in the anion. ...
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VK JAISWAL ENGLISH-CHEMICAL BONDING (ADVANCED)-ONE OR MORE ANSWER IS/ARE CORRECT
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  2. Stepwise hydrolysis of P(4)O(10) takes place via formation of :

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  3. Select the correct statement(s) about the compound NO[BF(4)]:

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  4. Which of the following molecule has as OO bonds?

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  5. CO(2) molecule is not isostructural with :

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  6. Which of the following have a linear structure?

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  7. Which of the following compound (s) is/are non-polar?

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  8. Non-polar molecule are:

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  9. Which of the following molecule species is/are having pi(2p) as H.O.M....

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  10. Correct order of b.p.t is /are:

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  11. Select correct statement(s) regarding sigma and pi bonds :

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  12. Which of the following species is/are having pi(2p) as HOMO (highest o...

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  13. Select correct order between given compounds .

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  14. Select the correct statement(s) regarding BF(2)NH(2) molecule:

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  15. Correct statement (s) about dipole moment of R(3)NO and R(3)PO is /are...

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  16. In which of the following compounds observed bond angle is found to be...

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  17. Two compounds PX(2)Y(3) and PX(3)Y(2) (Where P=phosphorous atom and X,...

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  18. Corrrect order of bond angle in the given compounds is/are:

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  19. The correct statement(s) is /are :

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  20. Consider the following reversible chemical reactions : A(2)(g)+B(2)...

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