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Consider the following compounds (1)H(...

Consider the following compounds
(1)`H_(3)CF` (2)`H_(2)CF_(2)` (3)` CH_(4)` (4)`H_(3)C CF_(3)` (5)`CH_(3)CH_(2)+` (6)`C_(2)H_(4)`
and calculate value of Y+X, (where X is the total number of compounds which have `H-C-H` bond angles equal to `109^(@)28'` and Y is the total number of compounds which have `H-C-H` bond angles greater than `109^(@)28'` and less than `120^(@)`

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The correct Answer is:
To solve the problem, we need to analyze the bond angles in the given compounds and categorize them based on the specified criteria. ### Step-by-Step Solution: 1. **Identify the Compounds**: We have the following compounds: - (1) H₃CF - (2) H₂CF₂ - (3) CH₄ - (4) H₃C CF₃ - (5) CH₃CH₂⁺ - (6) C₂H₄ 2. **Determine the Hybridization and Bond Angles**: - **(1) H₃CF**: - Carbon is sp³ hybridized. - Normal bond angle = 109° 28'. - Due to the electronegative fluorine atom, the H-C-H bond angle will be slightly greater than 109° 28'. - **Conclusion**: Y (greater than 109° 28'). - **(2) H₂CF₂**: - Carbon is sp³ hybridized. - Normal bond angle = 109° 28'. - The presence of two fluorine atoms increases the H-C-H bond angle, making it greater than 109° 28'. - **Conclusion**: Y (greater than 109° 28'). - **(3) CH₄**: - Carbon is sp³ hybridized. - Bond angle = 109° 28'. - **Conclusion**: X (equal to 109° 28'). - **(4) H₃C CF₃**: - Carbon is sp³ hybridized. - The presence of three fluorine atoms increases the H-C-H bond angle, making it greater than 109° 28'. - **Conclusion**: Y (greater than 109° 28'). - **(5) CH₃CH₂⁺**: - The positive charge on carbon affects the bond angles. - The bond angle will be slightly less than 109° 28' due to the positive charge but greater than 120°. - **Conclusion**: Y (greater than 109° 28' but less than 120°). - **(6) C₂H₄**: - Carbon is sp² hybridized. - Bond angle = 120°. - Due to steric effects, the bond angle will be less than 120°. - **Conclusion**: Y (greater than 109° 28' but less than 120°). 3. **Count X and Y**: - **X (H-C-H bond angles equal to 109° 28')**: - Only CH₄ contributes to X. - **X = 1**. - **Y (H-C-H bond angles greater than 109° 28' and less than 120°)**: - H₃CF, H₂CF₂, H₃C CF₃, CH₃CH₂⁺, and C₂H₄ contribute to Y. - **Y = 5**. 4. **Calculate Y + X**: - Y + X = 5 + 1 = 6. ### Final Answer: Y + X = 6.

To solve the problem, we need to analyze the bond angles in the given compounds and categorize them based on the specified criteria. ### Step-by-Step Solution: 1. **Identify the Compounds**: We have the following compounds: - (1) H₃CF - (2) H₂CF₂ - (3) CH₄ ...
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