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Structure of S(2)Cl(2) is analogous to :...

Structure of `S_(2)Cl_(2)` is analogous to :

A

`SOCl_(2)`

B

`CO_(2)`

C

`H_(2)S`

D

`H_(2)O_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which structure is analogous to \( S_2Cl_2 \), we will analyze the molecular structure of \( S_2Cl_2 \) and compare it with the structures of the given options. ### Step 1: Analyze the Structure of \( S_2Cl_2 \) 1. **Valence Electrons**: Each sulfur (S) atom has 6 valence electrons. Since there are 2 sulfur atoms and 2 chlorine (Cl) atoms, we can calculate the total number of valence electrons: \[ \text{Total valence electrons} = 2 \times 6 + 2 \times 7 = 12 + 14 = 26 \] 2. **Lewis Structure**: The structure can be drawn as follows: - Connect the two sulfur atoms with a single bond. - Connect each sulfur atom to one chlorine atom with single bonds. - Each sulfur atom will have 2 lone pairs of electrons remaining. The Lewis structure looks like this: ``` Cl | Cl - S - S | (Lone pairs) ``` ### Step 2: Compare with Given Options Now, we will analyze the structures of the given options one by one. #### Option A: \( SOCl_2 \) 1. **Structure**: Sulfur is bonded to one oxygen (double bond) and two chlorine atoms (single bonds). The structure is: ``` Cl | Cl - S = O | (Lone pair) ``` - **Lone pairs**: 1 on sulfur. - **Shape**: Not similar to \( S_2Cl_2 \). #### Option B: \( CO_2 \) 1. **Structure**: Carbon is bonded to two oxygen atoms with double bonds: ``` O = C = O ``` - **Shape**: Linear, not similar to \( S_2Cl_2 \). #### Option C: \( H_2S \) 1. **Structure**: Sulfur is bonded to two hydrogen atoms: ``` H | H - S (Lone pairs) ``` - **Lone pairs**: 2 on sulfur. - **Shape**: Bent, but not analogous to \( S_2Cl_2 \). #### Option D: \( H_2O_2 \) 1. **Structure**: The structure of hydrogen peroxide is: ``` H H | | O - O (Lone pairs) ``` - **Lone pairs**: 2 on each oxygen. - **Shape**: Similar to \( S_2Cl_2 \) as both have a central atom with two single bonds and two lone pairs. ### Conclusion After analyzing all options, the structure of \( H_2O_2 \) (Option D) is the most analogous to \( S_2Cl_2 \). **Final Answer**: The structure of \( S_2Cl_2 \) is analogous to **Option D: \( H_2O_2 \)**. ---
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VK JAISWAL ENGLISH-CHEMICAL BONDING (ADVANCED)-SUBJECTIVE PROBLEMS
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