Home
Class 12
CHEMISTRY
The correct statement(s) is /are :...

The correct statement(s) is /are :

A

Boiling point of m-hydroxybenzaldehyde is greater than o-hydroxybenzaldehyde

B

Boiling point of `CHCl_(3)` is higher than `CCl_(4)`

C

Melting point `BeCl_(2)` is higher than `BeF_(2)`

D

Boiling point HF is greater than `CH_(3)F`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the correct statements about the boiling and melting points of various compounds, we will analyze each statement step by step. ### Step-by-Step Solution: 1. **Boiling Point of Meta Hydroxybenzaldehyde vs. Ortho Hydroxybenzaldehyde**: - **Meta Hydroxybenzaldehyde**: The structure does not allow for significant intramolecular hydrogen bonding. - **Ortho Hydroxybenzaldehyde**: The ortho position allows for intramolecular hydrogen bonding, which stabilizes the molecule and increases the energy required to vaporize it. - **Conclusion**: The boiling point of ortho hydroxybenzaldehyde is greater than that of meta hydroxybenzaldehyde. - **Correct Statement**: **Incorrect** (the statement claims the opposite). 2. **Boiling Point of CHCl3 vs. Cl4**: - **CHCl3 (Chloroform)**: This molecule is polar due to the presence of the carbon atom, which creates a dipole moment. - **Cl4 (Tetrachlorine)**: This molecule is non-polar as the dipole moments of the chlorine atoms cancel each other out. - **Conclusion**: The boiling point of CHCl3 is greater than that of Cl4 due to its polar nature. - **Correct Statement**: **Correct**. 3. **Melting Point of BeCl2 vs. BeF2**: - **BeCl2**: The chloride ion (Cl-) is larger than the fluoride ion (F-), leading to lower polarization and higher melting point. - **BeF2**: The fluoride ion is smaller and more polarizable, leading to stronger interactions and a higher melting point. - **Conclusion**: The melting point of BeCl2 is lower than that of BeF2. - **Correct Statement**: **Incorrect** (the statement claims the opposite). 4. **Boiling Point of HF vs. CH3F**: - **HF (Hydrogen Fluoride)**: Exhibits strong hydrogen bonding due to the presence of only one hydrogen atom bonded to fluorine. - **CH3F (Fluoromethane)**: Although it is polar, the presence of three hydrogen atoms reduces the overall polarity compared to HF. - **Conclusion**: The boiling point of HF is greater than that of CH3F due to stronger hydrogen bonding in HF. - **Correct Statement**: **Correct**. ### Final Summary of Correct Statements: - The correct statements are: - Boiling point of CHCl3 is greater than Cl4. - Boiling point of HF is greater than CH3F.

To solve the question regarding the correct statements about the boiling and melting points of various compounds, we will analyze each statement step by step. ### Step-by-Step Solution: 1. **Boiling Point of Meta Hydroxybenzaldehyde vs. Ortho Hydroxybenzaldehyde**: - **Meta Hydroxybenzaldehyde**: The structure does not allow for significant intramolecular hydrogen bonding. - **Ortho Hydroxybenzaldehyde**: The ortho position allows for intramolecular hydrogen bonding, which stabilizes the molecule and increases the energy required to vaporize it. - **Conclusion**: The boiling point of ortho hydroxybenzaldehyde is greater than that of meta hydroxybenzaldehyde. ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING (ADVANCED)

    VK JAISWAL ENGLISH|Exercise MATCH THE COLUMN|21 Videos
  • CHEMICAL BONDING (ADVANCED)

    VK JAISWAL ENGLISH|Exercise ASSERTION-REASON TYPE QUESTIONS|57 Videos
  • CHEMICAL BONDING (ADVANCED)

    VK JAISWAL ENGLISH|Exercise Level 3|77 Videos
  • CHEMICAL BONDING (BASIC)

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|54 Videos

Similar Questions

Explore conceptually related problems

Select correct statement(s) is /are :

The correct statement (s) are

select the correct statement (s) :

select the correct statement (s) :

Choose the correct statement (s) :

select the correct statement (s) :

Select the correct statement (s) :

Select the correct statement (s) :

Select the correct statement (s) :

Select the correct statement (s) :

VK JAISWAL ENGLISH-CHEMICAL BONDING (ADVANCED)-ONE OR MORE ANSWER IS/ARE CORRECT
  1. Two compounds PX(2)Y(3) and PX(3)Y(2) (Where P=phosphorous atom and X,...

    Text Solution

    |

  2. Corrrect order of bond angle in the given compounds is/are:

    Text Solution

    |

  3. The correct statement(s) is /are :

    Text Solution

    |

  4. Consider the following reversible chemical reactions : A(2)(g)+B(2)...

    Text Solution

    |

  5. In which of the following molecules mu(exp) (observed dipole moment) i...

    Text Solution

    |

  6. Correct statement (s) regarding As(CH(3))F(2)Cl(2) molecule is/are:

    Text Solution

    |

  7. Which of the following species are involved

    Text Solution

    |

  8. Which of the following statements is correct?

    Text Solution

    |

  9. Which of the following species is/are not know?

    Text Solution

    |

  10. Select correct order between following compounds:

    Text Solution

    |

  11. Which of the following is (are) V-shaped?

    Text Solution

    |

  12. Which of the following equlibria would have highest and lowest value o...

    Text Solution

    |

  13. Which of the following process is/are assciated with change of hybridi...

    Text Solution

    |

  14. Which of the following are true?

    Text Solution

    |

  15. Which of the following statement is incorrect?

    Text Solution

    |

  16. Which of the following statements are not correct?

    Text Solution

    |

  17. In the structure of H(2)CSF(4), which of the following statement is/ar...

    Text Solution

    |

  18. In which compound compounds vacant hybride orbitals take part in bondi...

    Text Solution

    |

  19. Which of the following is true for N(2)O?

    Text Solution

    |

  20. Silane is more reactive than CH(4) towards Nu^(-) substitution due to...

    Text Solution

    |