Home
Class 12
CHEMISTRY
Calculate expression (x+y+z) for diatomi...

Calculate expression `(x+y+z)` for diatomic molecules.
where x=Total number of singly occupied molecular orbital (SOMO) in `O_(2)`.
y=Total number of singly occupied molecular orbital (SOMO) in `B_(2)`
z=Total number of singly occupied molecular orbital (SOMO) in `NO`.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to calculate the total number of singly occupied molecular orbitals (SOMO) for the diatomic molecules \( O_2 \), \( B_2 \), and \( NO \). We will denote these values as \( x \), \( y \), and \( z \) respectively, and then find the expression \( x + y + z \). ### Step 1: Calculate \( x \) for \( O_2 \) 1. **Determine the total number of electrons in \( O_2 \)**: - Oxygen has 8 electrons, so \( O_2 \) has \( 8 + 8 = 16 \) electrons. 2. **Write the molecular orbital electronic configuration**: - The configuration for \( O_2 \) is: \[ \sigma_{1s}^2 \sigma_{1s}^*^2 \sigma_{2s}^2 \sigma_{2s}^*^2 \sigma_{2p_z}^2 \pi_{2p_x}^2 \pi_{2p_y}^2 \pi_{2p_x}^*^1 \pi_{2p_y}^*^1 \] 3. **Count the singly occupied molecular orbitals (SOMO)**: - The \( \pi_{2p_x}^* \) and \( \pi_{2p_y}^* \) each have 1 electron, resulting in 2 SOMOs. - Thus, \( x = 2 \). ### Step 2: Calculate \( y \) for \( B_2 \) 1. **Determine the total number of electrons in \( B_2 \)**: - Boron has 5 electrons, so \( B_2 \) has \( 5 + 5 = 10 \) electrons. 2. **Write the molecular orbital electronic configuration**: - The configuration for \( B_2 \) is: \[ \sigma_{1s}^2 \sigma_{1s}^*^2 \sigma_{2s}^2 \sigma_{2s}^*^2 \pi_{2p_x}^2 \pi_{2p_y}^1 \] 3. **Count the singly occupied molecular orbitals (SOMO)**: - The \( \pi_{2p_x} \) and \( \pi_{2p_y} \) each have 1 electron, resulting in 2 SOMOs. - Thus, \( y = 2 \). ### Step 3: Calculate \( z \) for \( NO \) 1. **Determine the total number of electrons in \( NO \)**: - Nitrogen has 7 electrons and oxygen has 8 electrons, so \( NO \) has \( 7 + 8 = 15 \) electrons. 2. **Write the molecular orbital electronic configuration**: - The configuration for \( NO \) is: \[ \sigma_{1s}^2 \sigma_{1s}^*^2 \sigma_{2s}^2 \sigma_{2s}^*^2 \sigma_{2p_z}^2 \pi_{2p_x}^2 \pi_{2p_y}^2 \pi_{2p_x}^*^1 \] 3. **Count the singly occupied molecular orbitals (SOMO)**: - The \( \pi_{2p_x}^* \) has 1 electron, resulting in 1 SOMO. - Thus, \( z = 1 \). ### Step 4: Calculate \( x + y + z \) Now, we can sum the values: \[ x + y + z = 2 + 2 + 1 = 5 \] ### Final Answer: The value of the expression \( (x + y + z) \) is \( 5 \). ---
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING (ADVANCED)

    VK JAISWAL ENGLISH|Exercise ASSERTION-REASON TYPE QUESTIONS|57 Videos
  • CHEMICAL BONDING (BASIC)

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|54 Videos

Similar Questions

Explore conceptually related problems

How many orbitals are singly occupied in O_(2) molecule ?

Total number of acids/esters with molecular formula C_4H_8O_2 is

The main axis of diatomic molecule is z . The orbitals p_x and p_y overlap to form (a) pi -molecular orbital (b) sigma - molecular orbital (c) delta -molecular orbital (d)No bond will form

HOMO (highest occupied molecular orbital) of N_(2) molecule is (consider x-axis as an inter nuclear axis):

On thermal decomposition of ammonium dichromate, a gas ‘X’ in produced. Find the number of occupied molecular orbital of X.

Which of the following molecule species is/are having pi_(2p) as H.O.M.O (highest occupied molecular orbital) :

Which of the following molecule species is/are having pi_(2p) as H.O.M.O (highest occupied molecular orbital) :

H.O.M.O (Highest Occupied Molecular Orbital ) of CO molecular is :

The number of completely filled pi molecular orbitals in ground state of C_(2) is________.

Assertion B_(2) molecule is diamagnetic Reasoning The highest occupied molecular orbital is of sigma type .

VK JAISWAL ENGLISH-CHEMICAL BONDING (ADVANCED)-SUBJECTIVE PROBLEMS
  1. Consider the following elements A, B, C and D and their outer electron...

    Text Solution

    |

  2. Consider following four compounds: (i) C(x) O(y) (ii) C(x)O(y+1) ...

    Text Solution

    |

  3. Calculate expression (x+y+z) for diatomic molecules. where x=Total n...

    Text Solution

    |

  4. If Hund rule violate, then find the total number of species among foll...

    Text Solution

    |

  5. Consider the following table Than calculate value of experssion...

    Text Solution

    |

  6. Total number of species among following, in which bond angle is equal...

    Text Solution

    |

  7. Total number of unpaired electrons(s) present in both cationic and an...

    Text Solution

    |

  8. Total number of species which has/ have symmetrical electronic distrib...

    Text Solution

    |

  9. Total number of molecules, in which each covalent bond is comprised of...

    Text Solution

    |

  10. Total number of angle in SeCl(4) which are less than 90^(@).

    Text Solution

    |

  11. Consider the following species O(Me)(2), N(SiH(3))(3), CO, O(SiH(3))(2...

    Text Solution

    |

  12. Total number of molecules which can form H-bond among themselves. Si...

    Text Solution

    |

  13. Consider two covalent compounds AL(n(1)) and BL(n(2)), if central atom...

    Text Solution

    |

  14. Calculate the I-I distance in (Å) for given compound H(2)C(2) I(2) if ...

    Text Solution

    |

  15. There are some arrangements of atomic orbitals which are given below: ...

    Text Solution

    |

  16. Number of hybrid orbital C atoms which have 33% p-character in C(CN)(4...

    Text Solution

    |

  17. Max. no. of equal P-O bonds in P(2)O(7)^(4-) ion is :

    Text Solution

    |

  18. Consider the following species: (i) CH(3)^(+) (ii) (C(3)H(5))(3)Al...

    Text Solution

    |

  19. Calculate value of |x-y|, here x and y are the total number of bonds i...

    Text Solution

    |

  20. Consider the following compounds : (i) IF(5) " " (ii) ClI(4)^(-) "...

    Text Solution

    |