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Consider the following compounds : (i)...

Consider the following compounds :
`(i) IF_(5) " " (ii) ClI_(4)^(-) " " (iii) XeO_(2)F_(2) " " (iv) NH_(2)^(-) `
`(v) BCl_(3) " " (vi) BeCl_(2) " " (vii) AsCl_(4)^(+) " " (viii) B(OH)_(3)`
(ix) `NO_(2)^(-) " " (x) ClO_(2)^(+)`
Then calculate value of "x+y-z", here, x,y and z are total number of compounds in given compounds in which central atom used their all three p-orbitals, only two p-orbitals and only one p-orbital in hybridisation respectively .

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The correct Answer is:
To solve the problem, we need to analyze each compound to determine the hybridization of the central atom and categorize them based on the number of p-orbitals used in the hybridization. We will denote: - **x**: Total number of compounds where the central atom uses all three p-orbitals. - **y**: Total number of compounds where the central atom uses only two p-orbitals. - **z**: Total number of compounds where the central atom uses only one p-orbital. Let's analyze each compound step by step: ### Step 1: Analyze IF₅ - **Valence Electrons**: Iodine (I) has 7 valence electrons. There are 5 fluorine atoms contributing 5 electrons. - **Steric Number Calculation**: (7 + 5) / 2 = 6 - **Hybridization**: sp³d² - **p-orbitals Used**: All three p-orbitals are used. (Count: 1) ### Step 2: Analyze ClI₄⁻ - **Valence Electrons**: Chlorine (Cl) has 7, 4 iodine atoms contribute 4, and the negative charge adds 1. - **Steric Number Calculation**: (7 + 4 + 1) / 2 = 6 - **Hybridization**: sp³d² - **p-orbitals Used**: All three p-orbitals are used. (Count: 2) ### Step 3: Analyze XeO₂F₂ - **Valence Electrons**: Xenon (Xe) has 8, 2 oxygen atoms contribute 4, and 2 fluorine atoms contribute 2. - **Steric Number Calculation**: (8 + 4 + 2) / 2 = 7 - **Hybridization**: sp³d - **p-orbitals Used**: All three p-orbitals are used. (Count: 3) ### Step 4: Analyze NH₂⁻ - **Valence Electrons**: Nitrogen (N) has 5, and the negative charge adds 1. - **Steric Number Calculation**: (5 + 2 + 1) / 2 = 4 - **Hybridization**: sp³ - **p-orbitals Used**: All three p-orbitals are used. (Count: 4) ### Step 5: Analyze BCl₃ - **Valence Electrons**: Boron (B) has 3, and 3 chlorine atoms contribute 3. - **Steric Number Calculation**: (3 + 3) / 2 = 3 - **Hybridization**: sp² - **p-orbitals Used**: Only two p-orbitals are used. (Count: 1) ### Step 6: Analyze BeCl₂ - **Valence Electrons**: Beryllium (Be) has 2, and 2 chlorine atoms contribute 2. - **Steric Number Calculation**: (2 + 2) / 2 = 2 - **Hybridization**: sp - **p-orbitals Used**: Only one p-orbital is used. (Count: 1) ### Step 7: Analyze AsCl₄⁺ - **Valence Electrons**: Arsenic (As) has 5, 4 chlorine atoms contribute 4, and the positive charge subtracts 1. - **Steric Number Calculation**: (5 + 4 - 1) / 2 = 4 - **Hybridization**: sp³ - **p-orbitals Used**: All three p-orbitals are used. (Count: 5) ### Step 8: Analyze B(OH)₃ - **Valence Electrons**: Boron (B) has 3, and 3 hydroxyl groups contribute 3. - **Steric Number Calculation**: (3 + 3) / 2 = 3 - **Hybridization**: sp² - **p-orbitals Used**: Only two p-orbitals are used. (Count: 2) ### Step 9: Analyze NO₂⁻ - **Valence Electrons**: Nitrogen (N) has 5, 2 oxygen atoms contribute 4, and the negative charge adds 1. - **Steric Number Calculation**: (5 + 4 + 1) / 2 = 5 - **Hybridization**: sp² - **p-orbitals Used**: Only two p-orbitals are used. (Count: 3) ### Step 10: Analyze ClO₂⁺ - **Valence Electrons**: Chlorine (Cl) has 7, 2 oxygen atoms contribute 4, and the positive charge subtracts 1. - **Steric Number Calculation**: (7 + 4 - 1) / 2 = 5 - **Hybridization**: sp² - **p-orbitals Used**: Only two p-orbitals are used. (Count: 4) ### Summary of Counts - **x (3 p-orbitals used)**: 5 compounds (IF₅, ClI₄⁻, XeO₂F₂, NH₂⁻, AsCl₄⁺) - **y (2 p-orbitals used)**: 4 compounds (BCl₃, B(OH)₃, NO₂⁻, ClO₂⁺) - **z (1 p-orbital used)**: 1 compound (BeCl₂) ### Final Calculation Now we calculate the value of "x + y - z": - x = 5 - y = 4 - z = 1 So, \( x + y - z = 5 + 4 - 1 = 8 \). ### Final Answer The value of \( x + y - z \) is **8**.

To solve the problem, we need to analyze each compound to determine the hybridization of the central atom and categorize them based on the number of p-orbitals used in the hybridization. We will denote: - **x**: Total number of compounds where the central atom uses all three p-orbitals. - **y**: Total number of compounds where the central atom uses only two p-orbitals. - **z**: Total number of compounds where the central atom uses only one p-orbital. Let's analyze each compound step by step: ...
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