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Consider the following compounds (1)H(...

Consider the following compounds
(1)`H_(3)CF` (2)`H_(2)CF_(2)` (3)` CH_(4)` (4)`H_(3)C CF_(3)` (5)`CH_(3)CH_(3)` (6)`C_(2)H_(4)`
and calculate value of Y+X, (where X is the total number of compounds which have `H-C-H` bond angles equal to `109^(@)28'` and Y is the total number of compounds which have `H-C-H` bond angles greater than `109^(@)28'` and less than `120^(@)`

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The correct Answer is:
To solve the problem, we need to analyze the given compounds and determine the H-C-H bond angles for each of them. We will categorize them into two groups: those with bond angles equal to 109°28' (X) and those with bond angles greater than 109°28' and less than 120° (Y). Finally, we will calculate the value of Y + X. ### Step-by-Step Solution: 1. **Identify the Compounds:** We have the following compounds: - (1) H₃CF - (2) H₂CF₂ - (3) CH₄ - (4) H₃C-CF₃ - (5) CH₃CH₃ - (6) C₂H₄ 2. **Determine the H-C-H Bond Angles:** - **(1) H₃CF:** - Carbon is bonded to 3 hydrogens and 1 fluorine. - Steric number = 4 (3 H + 1 F). - Hybridization = sp³. - Bond angle = 109°28'. - **(2) H₂CF₂:** - Carbon is bonded to 2 hydrogens and 2 fluorines. - Steric number = 4 (2 H + 2 F). - Hybridization = sp³. - Bond angle = 109°28'. - **(3) CH₄:** - Carbon is bonded to 4 hydrogens. - Steric number = 4 (4 H). - Hybridization = sp³. - Bond angle = 109°28'. - **(4) H₃C-CF₃:** - One carbon is bonded to 3 hydrogens and the other to 3 fluorines. - The H-C-H bond angle is still 109°28' (due to sp³ hybridization). - **(5) CH₃CH₃:** - Each carbon is bonded to 3 hydrogens. - Steric number = 4 (4 H). - Hybridization = sp³. - Bond angle = 109°28'. - **(6) C₂H₄:** - Each carbon is bonded to 2 hydrogens and 1 carbon (double bond). - Steric number = 3 (2 H + 1 C). - Hybridization = sp². - Bond angle = 120°. 3. **Count the Compounds:** - **Compounds with H-C-H bond angles equal to 109°28' (X):** - (1) H₃CF - (2) H₂CF₂ - (3) CH₄ - (4) H₃C-CF₃ - (5) CH₃CH₃ - Total = 5 compounds (X = 5). - **Compounds with H-C-H bond angles greater than 109°28' and less than 120° (Y):** - (6) C₂H₄ has a bond angle of 120°. - No compounds fall into this category (Y = 0). 4. **Calculate Y + X:** - Y + X = 0 + 5 = 5. ### Final Answer: The value of Y + X is **5**.

To solve the problem, we need to analyze the given compounds and determine the H-C-H bond angles for each of them. We will categorize them into two groups: those with bond angles equal to 109°28' (X) and those with bond angles greater than 109°28' and less than 120° (Y). Finally, we will calculate the value of Y + X. ### Step-by-Step Solution: 1. **Identify the Compounds:** We have the following compounds: - (1) H₃CF - (2) H₂CF₂ ...
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