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A certain ideal gas undergoes a polytrop...

A certain ideal gas undergoes a polytropic process `PV^(n)` = constant such that the molar specific heat during the process is negative. If the ratio of the specific heats of the gas be `gamma`, then the range of values of `n` will be

A

(a)`0 lt n lt gamma`

B

(b)`1 lt n lt gamma`

C

(c)`n = gamma`

D

(d)`n gt gamma`

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The correct Answer is:
To solve the problem regarding the range of values of \( n \) for an ideal gas undergoing a polytropic process with negative molar specific heat, we can follow these steps: ### Step 1: Understand the Polytropic Process In a polytropic process, the relationship between pressure \( P \), volume \( V \), and the polytropic index \( n \) is given by: \[ PV^n = \text{constant} \] ### Step 2: Molar Specific Heat in a Polytropic Process The molar specific heat \( C \) during a polytropic process can be expressed as: \[ C = C_v + \frac{R}{1 - n} \] where \( C_v \) is the molar specific heat at constant volume, and \( R \) is the universal gas constant. ### Step 3: Condition for Negative Molar Specific Heat For the molar specific heat \( C \) to be negative, we set the equation: \[ C < 0 \] Substituting the expression for \( C \): \[ C_v + \frac{R}{1 - n} < 0 \] ### Step 4: Rearranging the Inequality Rearranging the inequality gives us: \[ \frac{R}{1 - n} < -C_v \] This implies: \[ 1 - n < -\frac{R}{C_v} \] or \[ n > 1 + \frac{R}{C_v} \] ### Step 5: Relating \( C_v \) and \( \gamma \) Using the relationship between specific heats, we know: \[ \gamma = \frac{C_p}{C_v} = 1 + \frac{R}{C_v} \] From this, we can express \( C_v \) in terms of \( \gamma \): \[ C_v = \frac{R}{\gamma - 1} \] ### Step 6: Substitute \( C_v \) in the Inequality Substituting \( C_v \) into the inequality: \[ n > 1 + \frac{R}{\frac{R}{\gamma - 1}} = 1 + (\gamma - 1) = \gamma \] ### Step 7: Final Range for \( n \) Thus, we have: \[ n > \gamma \] ### Step 8: Conclusion Since \( n \) must also be less than \( 1 \) for the process to be polytropic with negative specific heat, we conclude: \[ 1 < n < \gamma \] ### Final Answer The range of values for \( n \) is: \[ 1 < n < \gamma \]

To solve the problem regarding the range of values of \( n \) for an ideal gas undergoing a polytropic process with negative molar specific heat, we can follow these steps: ### Step 1: Understand the Polytropic Process In a polytropic process, the relationship between pressure \( P \), volume \( V \), and the polytropic index \( n \) is given by: \[ PV^n = \text{constant} \] ...
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