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One mole of air (C(V) = 5R//2) is confin...

One mole of air `(C_(V) = 5R//2)` is confined at atmospheric pressure in a cylinder with a piston at `0^(@)C`. The initial volume occupied by gas is`V`. After the equivalent of `13200 J` of heat is transferred to it, the volume of gas `V` is nearly `(1 atm = 10^(5) N//m^(3))`

A

`37 L`

B

`22 L`

C

`60 L`

D

`30 L`

Text Solution

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The correct Answer is:
To solve the problem step by step, we will use the concepts of thermodynamics, specifically the ideal gas law and the relationship between heat, temperature, and volume changes in gases. ### Step 1: Identify the given values - Number of moles of air, \( n = 1 \) mole - Heat added, \( \Delta Q = 13200 \) J - Specific heat at constant volume, \( C_V = \frac{5R}{2} \) - Initial temperature, \( T_i = 0^\circ C = 273 \, \text{K} \) - Initial pressure, \( P = 1 \, \text{atm} = 10^5 \, \text{N/m}^2 \) ### Step 2: Calculate \( C_P \) using the relation \( C_P - C_V = R \) Using Meyer’s equation: \[ C_P = C_V + R = \frac{5R}{2} + R = \frac{5R}{2} + \frac{2R}{2} = \frac{7R}{2} \] ### Step 3: Calculate the initial volume using the ideal gas law The ideal gas law is given by: \[ PV = nRT \] Substituting the known values: \[ V_i = \frac{nRT_i}{P} = \frac{1 \times R \times 273}{10^5} \] Using \( R = 8.3 \, \text{J/(mol K)} \): \[ V_i = \frac{1 \times 8.3 \times 273}{10^5} \approx 0.0227 \, \text{m}^3 = 22.7 \, \text{liters} \] ### Step 4: Relate heat added to change in volume At constant pressure, the heat added can be expressed as: \[ \Delta Q = n C_P \Delta T \] Rearranging gives: \[ \Delta T = \frac{\Delta Q}{n C_P} \] Substituting \( C_P = \frac{7R}{2} \): \[ \Delta T = \frac{\Delta Q}{n \cdot \frac{7R}{2}} = \frac{2 \Delta Q}{7R} \] ### Step 5: Substitute \( \Delta Q \) and \( R \) to find \( \Delta T \) \[ \Delta T = \frac{2 \times 13200}{7 \times 8.3} \approx \frac{26400}{58.1} \approx 454.3 \, \text{K} \] ### Step 6: Calculate the final temperature \[ T_f = T_i + \Delta T = 273 + 454.3 \approx 727.3 \, \text{K} \] ### Step 7: Calculate the final volume using the ideal gas law again Using the ideal gas law for the final state: \[ V_f = \frac{nRT_f}{P} = \frac{1 \times 8.3 \times 727.3}{10^5} \] Calculating: \[ V_f \approx \frac{6048.19}{10^5} \approx 0.0604 \, \text{m}^3 = 60.4 \, \text{liters} \] ### Final Answer The final volume of the gas is approximately **60.4 liters**.

To solve the problem step by step, we will use the concepts of thermodynamics, specifically the ideal gas law and the relationship between heat, temperature, and volume changes in gases. ### Step 1: Identify the given values - Number of moles of air, \( n = 1 \) mole - Heat added, \( \Delta Q = 13200 \) J - Specific heat at constant volume, \( C_V = \frac{5R}{2} \) - Initial temperature, \( T_i = 0^\circ C = 273 \, \text{K} \) - Initial pressure, \( P = 1 \, \text{atm} = 10^5 \, \text{N/m}^2 \) ...
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