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Oxygen gas is made to undergo a process ...

Oxygen gas is made to undergo a process in which its molar heat capacity `C` depends on its absolute temperature `T` as `C = alpha T`. Work done by it when heated from an initial temperature `T_(0)` to a final temperature `2 T_(0)`, will be

A

`4 alpha T_(0)`

B

`(alpha T_(0) - R) (3 T_(0))/(2)`

C

`(3 alpha T_(0) - 5 R) (T_(0))/(2)`

D

none of these

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The correct Answer is:
To solve the problem of finding the work done by oxygen gas when it is heated from an initial temperature \( T_0 \) to a final temperature \( 2T_0 \) with a molar heat capacity \( C = \alpha T \), we can follow these steps: ### Step 1: Understand the relationship between heat, molar heat capacity, and temperature change The heat \( Q \) added to the gas can be expressed as: \[ Q = nC\Delta T \] where \( n \) is the number of moles, \( C \) is the molar heat capacity, and \( \Delta T \) is the change in temperature. ### Step 2: Substitute the expression for molar heat capacity Given that \( C = \alpha T \), we can substitute this into the equation for heat: \[ Q = n(\alpha T)\Delta T \] ### Step 3: Determine the change in temperature The change in temperature \( \Delta T \) from \( T_0 \) to \( 2T_0 \) is: \[ \Delta T = 2T_0 - T_0 = T_0 \] ### Step 4: Substitute \( \Delta T \) into the heat equation Now, substituting \( \Delta T \) into the equation for heat: \[ Q = n\alpha T (T_0) \] ### Step 5: Express \( Q \) in terms of integration Since \( C = \alpha T \) varies with temperature, we need to integrate to find the total heat added: \[ Q = n\int_{T_0}^{2T_0} \alpha T \, dT \] ### Step 6: Perform the integration Integrating \( Q \): \[ Q = n\alpha \left[ \frac{T^2}{2} \right]_{T_0}^{2T_0} = n\alpha \left( \frac{(2T_0)^2}{2} - \frac{(T_0)^2}{2} \right) \] \[ = n\alpha \left( \frac{4T_0^2}{2} - \frac{T_0^2}{2} \right) = n\alpha \left( \frac{3T_0^2}{2} \right) \] ### Step 7: Apply the first law of thermodynamics According to the first law of thermodynamics: \[ Q = \Delta U + W \] where \( \Delta U \) is the change in internal energy and \( W \) is the work done by the gas. ### Step 8: Calculate the change in internal energy for an ideal gas For an ideal gas, the change in internal energy \( \Delta U \) can be expressed as: \[ \Delta U = nC_V\Delta T \] For oxygen, \( C_V = \frac{5}{2}R \), thus: \[ \Delta U = n\left(\frac{5}{2}R\right)(T_0) = \frac{5}{2}nRT_0 \] ### Step 9: Substitute \( Q \) and \( \Delta U \) into the first law equation Substituting into the first law: \[ n\alpha \left( \frac{3T_0^2}{2} \right) = \frac{5}{2}nRT_0 + W \] ### Step 10: Solve for work \( W \) Rearranging gives: \[ W = n\alpha \left( \frac{3T_0^2}{2} \right) - \frac{5}{2}nRT_0 \] ### Step 11: Factor out common terms Factoring out \( nT_0 \): \[ W = nT_0 \left( \frac{3\alpha T_0}{2} - \frac{5R}{2} \right) \] ### Final Expression The work done by the gas when heated from \( T_0 \) to \( 2T_0 \) is: \[ W = nT_0 \left( \frac{3\alpha T_0 - 5R}{2} \right) \]

To solve the problem of finding the work done by oxygen gas when it is heated from an initial temperature \( T_0 \) to a final temperature \( 2T_0 \) with a molar heat capacity \( C = \alpha T \), we can follow these steps: ### Step 1: Understand the relationship between heat, molar heat capacity, and temperature change The heat \( Q \) added to the gas can be expressed as: \[ Q = nC\Delta T \] where \( n \) is the number of moles, \( C \) is the molar heat capacity, and \( \Delta T \) is the change in temperature. ...
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