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Which of the following statement is true...

Which of the following statement is true?

A

Absolute zero degree temperature is not zero enery temperature.

B

Two different gases at the same temperature pressure have equal root mean square velocities.

C

The rms speed of the molecules of different ideal gases, maintained at the same temperature are the same.

D

Given sample of 1cc of hydrogen and 1cc of oxygen both at N.T.P.,oxygen sample has a large number of molecules.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement is true among the given options, let's analyze each statement step by step. ### Step 1: Analyze Statement A **Statement A:** Absolute zero degree temperature is not zero energy temperature. - At absolute zero (0 Kelvin), the kinetic energy of gas molecules approaches zero. - However, according to quantum mechanics, particles still possess some potential energy due to their inherent quantum states. - Therefore, while kinetic energy is zero, total energy (kinetic + potential) is not zero. **Conclusion:** Statement A is true. ### Step 2: Analyze Statement B **Statement B:** Two different gases at the same temperature and pressure have equal root mean square velocity. - The root mean square (RMS) velocity is given by the formula: \[ V_{rms} = \sqrt{\frac{3RT}{M}} \] where \( R \) is the gas constant, \( T \) is the temperature, and \( M \) is the molar mass of the gas. - For two different gases at the same temperature, their RMS velocities will depend on their molar masses. Since the molar masses are different, the RMS velocities will also be different. **Conclusion:** Statement B is false. ### Step 3: Analyze Statement C **Statement C:** The RMS speed of the molecules of different ideal gases maintained at the same temperature are the same. - This statement is similar to Statement B and relies on the same formula for RMS velocity. - Since different gases have different molar masses, their RMS speeds will not be the same even if the temperature is the same. **Conclusion:** Statement C is false. ### Step 4: Analyze Statement D **Statement D:** Given a sample of one cubic centimeter of hydrogen and one cubic centimeter of oxygen both at NTP, the oxygen sample has a larger number of molecules. - According to Avogadro's law, equal volumes of gases at the same temperature and pressure contain an equal number of molecules, regardless of the type of gas. - Therefore, one cubic centimeter of hydrogen and one cubic centimeter of oxygen at the same conditions will have the same number of molecules. **Conclusion:** Statement D is false. ### Final Conclusion After analyzing all four statements, we find that only **Statement A** is true.
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