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Which of the following is//are correct. ...

Which of the following `is//are` correct.
The following reaction occurs: ltrgt `CS_(2) + 3Cl_(2) overset(Delta)rarr C Cl_(4) + S_(2) Cl_(2)`
`1.0 g` of `CS_(2)` and `2.0 g` of `Cl_(2)` reacts.

A

`0.714 g CS_(2)` is used in the reaction.

B

`0.286 g CS_(2)` is in formed.

C

`1.45 g of C Cl_(4)` is formed

D

`0.8 g Cl_(2)` is in excess

Text Solution

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The correct Answer is:
To solve the problem step by step, we will first analyze the reaction and then calculate the moles of the reactants involved. ### Step 1: Write the balanced chemical equation The given reaction is: \[ \text{CS}_2 + 3\text{Cl}_2 \overset{\Delta}{\rightarrow} \text{CCl}_4 + \text{S}_2\text{Cl}_2 \] ### Step 2: Calculate the moles of CS₂ To find the moles of CS₂, we use the formula: \[ \text{Moles} = \frac{\text{Given mass}}{\text{Molar mass}} \] The molar mass of CS₂ is calculated as follows: - Carbon (C) = 12 g/mol - Sulfur (S) = 32 g/mol So, the molar mass of CS₂: \[ 12 + 2 \times 32 = 12 + 64 = 76 \, \text{g/mol} \] Now, substituting the values: \[ \text{Moles of CS}_2 = \frac{1 \, \text{g}}{76 \, \text{g/mol}} = 0.013 \, \text{moles} \] ### Step 3: Calculate the moles of Cl₂ The molar mass of Cl₂ is: - Chlorine (Cl) = 35.5 g/mol - Therefore, the molar mass of Cl₂: \[ 2 \times 35.5 = 71 \, \text{g/mol} \] Now, substituting the values: \[ \text{Moles of Cl}_2 = \frac{2 \, \text{g}}{71 \, \text{g/mol}} \approx 0.028 \, \text{moles} \] ### Step 4: Determine the limiting reagent From the balanced equation, we see that 1 mole of CS₂ reacts with 3 moles of Cl₂. Therefore, for 0.013 moles of CS₂, the required moles of Cl₂ are: \[ 0.013 \, \text{moles of CS}_2 \times 3 = 0.039 \, \text{moles of Cl}_2 \] Since we only have 0.028 moles of Cl₂ available, Cl₂ is the limiting reagent. ### Step 5: Calculate the amount of CS₂ that reacts Since Cl₂ is limiting, we will use all of it. The moles of CS₂ that will react with 0.028 moles of Cl₂ can be calculated as: \[ \text{Moles of CS}_2 \text{ that reacts} = \frac{0.028}{3} \approx 0.00933 \, \text{moles} \] ### Step 6: Calculate the mass of CS₂ used To find the mass of CS₂ that reacted: \[ \text{Mass of CS}_2 \text{ used} = \text{Moles} \times \text{Molar mass} \] \[ = 0.00933 \, \text{moles} \times 76 \, \text{g/mol} \approx 0.71 \, \text{g} \] ### Step 7: Calculate the remaining mass of CS₂ The initial mass of CS₂ was 1 g, so the remaining mass is: \[ \text{Remaining mass of CS}_2 = 1 \, \text{g} - 0.71 \, \text{g} = 0.29 \, \text{g} \] ### Step 8: Calculate the amount of products formed Since the reaction produces 1 mole of CCl₄ and 1 mole of S₂Cl₂ for every 3 moles of Cl₂, the moles of products formed will be equal to the moles of Cl₂ used: \[ \text{Moles of CCl}_4 = \text{Moles of S}_2\text{Cl}_2 = 0.028 \, \text{moles} \] ### Step 9: Calculate the mass of CCl₄ formed The molar mass of CCl₄ is: \[ 12 + 4 \times 35.5 = 12 + 142 = 154 \, \text{g/mol} \] \[ \text{Mass of CCl}_4 = 0.028 \, \text{moles} \times 154 \, \text{g/mol} \approx 4.32 \, \text{g} \] ### Conclusion 1. 0.71 g of CS₂ is used in the reaction. 2. 0.29 g of CS₂ is left. 3. 4.32 g of CCl₄ is formed. 4. Cl₂ is the limiting reagent and is completely used up.

To solve the problem step by step, we will first analyze the reaction and then calculate the moles of the reactants involved. ### Step 1: Write the balanced chemical equation The given reaction is: \[ \text{CS}_2 + 3\text{Cl}_2 \overset{\Delta}{\rightarrow} \text{CCl}_4 + \text{S}_2\text{Cl}_2 \] ### Step 2: Calculate the moles of CS₂ To find the moles of CS₂, we use the formula: ...
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