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For the redox reaction: Cr(2)O(7)^(2-)...

For the redox reaction:
`Cr_(2)O_(7)^(2-)+H^(o+)+NirarrCr^(3+)+Ni^(2)+H_(2)O`
The correct coefficient of the reactants for the balanced reaction are:

A

`Cr_(2)O_(7)^(2-)=1, Ni=3, H^(o+)=14`

B

`Cr_(2)O_(7)^(2-)=3, Ni=3, H^(o+)=12`

C

`Cr_(2)O_(7)^(2-)=2, Ni=3, H^(o+)=14`

D

`Cr_(2)O_(7)^(2-)=1, Ni=1, H^(o+)=16`

Text Solution

AI Generated Solution

The correct Answer is:
To balance the redox reaction given, we will follow the ion-electron method, which involves separating the oxidation and reduction half-reactions. Here’s a step-by-step solution: ### Step 1: Identify the oxidation and reduction half-reactions In the reaction: \[ \text{Cr}_2\text{O}_7^{2-} + \text{H}^+ + \text{Ni} \rightarrow \text{Cr}^{3+} + \text{Ni}^{2+} + \text{H}_2\text{O} \] - **Oxidation half-reaction**: Nickel (Ni) is oxidized to Nickel ion (Ni²⁺). - **Reduction half-reaction**: Dichromate ion (Cr₂O₇²⁻) is reduced to Chromium ion (Cr³⁺). ### Step 2: Write the oxidation half-reaction Nickel is oxidized as follows: \[ \text{Ni} \rightarrow \text{Ni}^{2+} + 2e^- \] This indicates that each nickel atom loses 2 electrons. ### Step 3: Write the reduction half-reaction The reduction of dichromate can be written as: \[ \text{Cr}_2\text{O}_7^{2-} + 14\text{H}^+ + 6e^- \rightarrow 2\text{Cr}^{3+} + 7\text{H}_2\text{O} \] Here, we balance the chromium atoms, oxygen atoms (using water), and hydrogen ions. ### Step 4: Balance the electrons To balance the electrons lost in oxidation with those gained in reduction, we need to multiply the oxidation half-reaction by 3 (since 3 Ni will produce 6 electrons): \[ 3\text{Ni} \rightarrow 3\text{Ni}^{2+} + 6e^- \] ### Step 5: Combine the half-reactions Now we can combine the balanced half-reactions: \[ 3\text{Ni} + \text{Cr}_2\text{O}_7^{2-} + 14\text{H}^+ \rightarrow 3\text{Ni}^{2+} + 2\text{Cr}^{3+} + 7\text{H}_2\text{O} \] ### Step 6: Identify the coefficients of the reactants From the balanced equation, we can identify the coefficients of the reactants: - Coefficient of Ni = 3 - Coefficient of Cr₂O₇²⁻ = 1 - Coefficient of H⁺ = 14 ### Final Answer The correct coefficients of the reactants for the balanced reaction are: - Ni: 3 - Cr₂O₇²⁻: 1 - H⁺: 14

To balance the redox reaction given, we will follow the ion-electron method, which involves separating the oxidation and reduction half-reactions. Here’s a step-by-step solution: ### Step 1: Identify the oxidation and reduction half-reactions In the reaction: \[ \text{Cr}_2\text{O}_7^{2-} + \text{H}^+ + \text{Ni} \rightarrow \text{Cr}^{3+} + \text{Ni}^{2+} + \text{H}_2\text{O} \] - **Oxidation half-reaction**: Nickel (Ni) is oxidized to Nickel ion (Ni²⁺). - **Reduction half-reaction**: Dichromate ion (Cr₂O₇²⁻) is reduced to Chromium ion (Cr³⁺). ...
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