Home
Class 11
CHEMISTRY
Balance the following redox reactions. ...

Balance the following redox reactions.
Coppoer reacts with nitric acid, a brown, gas is formed and solution turns blue.
`Cu+NO_(3)^(ө)rarrNO_(2)+Cu^(2+)`

Text Solution

AI Generated Solution

The correct Answer is:
To balance the redox reaction of copper reacting with nitric acid, we will follow these steps: ### Step 1: Write the skeletal equation The skeletal equation provided is: \[ \text{Cu} + \text{NO}_3^- \rightarrow \text{NO}_2 + \text{Cu}^{2+} \] ### Step 2: Identify oxidation and reduction half-reactions 1. **Oxidation half-reaction**: Copper (Cu) is oxidized to copper ions (Cu²⁺). \[ \text{Cu} \rightarrow \text{Cu}^{2+} + 2e^- \] 2. **Reduction half-reaction**: Nitrate ion (NO₃⁻) is reduced to nitrogen dioxide (NO₂). \[ \text{NO}_3^- + e^- \rightarrow \text{NO}_2 \] ### Step 3: Balance the half-reactions 1. **Oxidation half-reaction**: - The oxidation half-reaction is already balanced in terms of atoms and charge: \[ \text{Cu} \rightarrow \text{Cu}^{2+} + 2e^- \] 2. **Reduction half-reaction**: - The reduction half-reaction needs to balance oxygen and hydrogen. - We have 3 oxygen on the left and 2 on the right, so we add 1 water molecule to the right: \[ \text{NO}_3^- + e^- \rightarrow \text{NO}_2 + \text{H}_2\text{O} \] - Now, we have 2 hydrogen on the right, so we add 2 H⁺ ions to the left: \[ 2\text{H}^+ + \text{NO}_3^- + e^- \rightarrow \text{NO}_2 + \text{H}_2\text{O} \] ### Step 4: Equalize the number of electrons transferred - The oxidation half-reaction releases 2 electrons, while the reduction half-reaction consumes only 1 electron. To equalize, we multiply the reduction half-reaction by 2: \[ 2\text{H}^+ + 2\text{NO}_3^- + 2e^- \rightarrow 2\text{NO}_2 + 2\text{H}_2\text{O} \] ### Step 5: Combine the half-reactions Now we can add the two half-reactions together: 1. From the oxidation half-reaction: \[ \text{Cu} \rightarrow \text{Cu}^{2+} + 2e^- \] 2. From the modified reduction half-reaction: \[ 2\text{H}^+ + 2\text{NO}_3^- + 2e^- \rightarrow 2\text{NO}_2 + 2\text{H}_2\text{O} \] Combining these gives: \[ \text{Cu} + 2\text{H}^+ + 2\text{NO}_3^- \rightarrow \text{Cu}^{2+} + 2\text{NO}_2 + 2\text{H}_2\text{O} \] ### Step 6: Final balanced equation The final balanced redox reaction is: \[ \text{Cu} + 4\text{H}^+ + 2\text{NO}_3^- \rightarrow \text{Cu}^{2+} + 2\text{NO}_2 + 2\text{H}_2\text{O} \]

To balance the redox reaction of copper reacting with nitric acid, we will follow these steps: ### Step 1: Write the skeletal equation The skeletal equation provided is: \[ \text{Cu} + \text{NO}_3^- \rightarrow \text{NO}_2 + \text{Cu}^{2+} \] ### Step 2: Identify oxidation and reduction half-reactions 1. **Oxidation half-reaction**: Copper (Cu) is oxidized to copper ions (Cu²⁺). ...
Promotional Banner

Topper's Solved these Questions

  • REDOX REACTIONS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Linked Comprehension)|24 Videos
  • REDOX REACTIONS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Multiple Correct)|32 Videos
  • REDOX REACTIONS

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 2.2|18 Videos
  • PURIFICATION OF ORGANIC COMPOUNDS AND QUALITATIVE AND QUANTITATIVE ANALYSIS

    CENGAGE CHEMISTRY ENGLISH|Exercise Assertion Reasoning Type|5 Videos
  • S-BLOCK GROUP 1 - ALKALI METALS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|8 Videos

Similar Questions

Explore conceptually related problems

Write a balanced equaiton when copper reacts with nitric acid, a brown gas is fromed and the solution turns blue.

Divide the following redox reactions into oxidation and reduction half reactions. Zn + Cu^(2+) to Zn&(2+) + Cu

Balance the following reaction in acidic medium. CuS+NO_(3)^(ө)rarrcu^(2+)+S_(8)+NO

Balance the following half-reactions in acidic medium: (a) IO_(3)^(Ө)(aq) rarr I_(3)^(Ө)(aq)

Write the balanced chemical equation for each of the following reactions: Ferric hydroxide reacts with nitric acid.

Classify the following as oxidation and reduction reaction, also complete the reaction. Cu to Cu^(2+)

Balance the following redox reactions by ion-electron method. H_(2)O_(2)(aq)+Fe^(2+)(aq)toFe^(3+)(aq)+H_(2)O(l) (in acidic solution)

Balance the following by ion electron method in acidic medium. CIO_(3)^(ө)+I_(2)rarrIO_(3)+CI^(ө)

Balance the following by ion electron method is basic medium. NO_(3)^(ө)+Znrarr Zn^(2+)+NH_(4)^(oplus) .

Classify the following reactions as combination, displacement, decomposition or neutralization reactions. Cu+2AgNO_3 to Cu(NO_3)_2 + 2Ag

CENGAGE CHEMISTRY ENGLISH-REDOX REACTIONS-Exercise
  1. Write correctly balanced equaitons for the following redox reaction. U...

    Text Solution

    |

  2. In question 10, state which element is oxidised by which element and w...

    Text Solution

    |

  3. Balance the following redox reactions. Coppoer reacts with nitric ac...

    Text Solution

    |

  4. Write correctly balanced half reactions and overall equations for the ...

    Text Solution

    |

  5. Starting with correctly balanced half reactions, write the overall net...

    Text Solution

    |

  6. Assign oxidation numbers to the elements in the following ionic compou...

    Text Solution

    |

  7. Calculate the oxidation number of the underlines elements: a. underl...

    Text Solution

    |

  8. Calculate the oxidation number of the underlined elements in the follo...

    Text Solution

    |

  9. What is the oxidation number of the underlined elements? a. H(2)und...

    Text Solution

    |

  10. Balance the following equation by oxidation number method in acidic me...

    Text Solution

    |

  11. Balance the following equations. NO(3)^(-)+H(2)StoHSO(4)^(-)+NH(4)^(...

    Text Solution

    |

  12. Balance the following equations by the ion electron method: a. MnO(4...

    Text Solution

    |

  13. Balance the following equations a. Fe^(2+) + Sn^(+2) rarr Sn^(4+) + ...

    Text Solution

    |

  14. Balance the following equations by ion electron method: Cr(2)O(7)^(2...

    Text Solution

    |

  15. Balance the following equations by ion electron (half reaction) method...

    Text Solution

    |

  16. Indicate in the following reactions which of the reactants, if any, ar...

    Text Solution

    |

  17. A mole of N(2)H(4) loses 10 mol of electrons to form a new compound Y....

    Text Solution

    |

  18. In the reaction: Cr(2)O(7)^(2-) + 14H^(o+) + 6I^(Ө) rarr2Cr^(3+) + 3...

    Text Solution

    |

  19. In the following equation, MnO(2) acts as MnO(4)^(2-) + 2H(2)O + 2E...

    Text Solution

    |

  20. Balance the following equations by ion electron method: a. CuO + NH(...

    Text Solution

    |