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Cr(2)O(7)^(2-)+Xoverset(H^(o+))rarrCr^(3...

`Cr_(2)O_(7)^(2-)+Xoverset(H^(o+))rarrCr^(3+)+H_(2)O+ "oxidised product" of X, X` in the above reaction cannot be

A

`C_(2)O_(4)^(2-)`

B

`Fe^(2+)`

C

`SO_(4)^(2-)`

D

`SO_(2-)`

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The correct Answer is:
To solve the problem, we need to determine which of the given options cannot be oxidized in the reaction involving the dichromate ion \( \text{Cr}_2\text{O}_7^{2-} \) in an acidic medium, producing \( \text{Cr}^{3+} \) and water, along with the oxidized product of \( X \). ### Step-by-Step Solution: 1. **Identify the Reactants and Products**: The reaction is: \[ \text{Cr}_2\text{O}_7^{2-} + X + 2H^+ \rightarrow 2\text{Cr}^{3+} + H_2O + \text{oxidized product of } X \] Here, \( X \) is the substance that is being oxidized. 2. **Understand Oxidation**: Oxidation involves an increase in the oxidation state of an element. We need to check the oxidation states of the elements in \( X \) to determine if they can be oxidized further. 3. **Evaluate Possible Options for \( X \)**: Let's analyze the common candidates for \( X \) and their oxidation states. - **Option 1: \( \text{C}_2\text{O}_4^{2-} \) (Oxalate Ion)**: - The oxidation state of carbon in \( \text{C}_2\text{O}_4^{2-} \) is +3. - It can be oxidized to a higher oxidation state (e.g., to \( \text{CO}_2 \)). - **Conclusion**: This can be oxidized. - **Option 2: \( \text{Fe}^{2+} \)**: - The oxidation state of iron is +2. - It can be oxidized to +3 or higher oxidation states. - **Conclusion**: This can be oxidized. - **Option 3: \( \text{SO}_4^{2-} \) (Sulfate Ion)**: - The oxidation state of sulfur in \( \text{SO}_4^{2-} \) is +6. - This is the highest oxidation state for sulfur; it cannot be oxidized further. - **Conclusion**: This cannot be oxidized. - **Option 4: \( \text{SO}_3^{2-} \) (Sulfite Ion)**: - The oxidation state of sulfur in \( \text{SO}_3^{2-} \) is +4. - It can be oxidized to +6 (to \( \text{SO}_4^{2-} \)). - **Conclusion**: This can be oxidized. 4. **Final Conclusion**: The substance \( X \) that cannot be oxidized in the given reaction is \( \text{SO}_4^{2-} \). ### Answer: **SO4^(2-) cannot be oxidized further.**

To solve the problem, we need to determine which of the given options cannot be oxidized in the reaction involving the dichromate ion \( \text{Cr}_2\text{O}_7^{2-} \) in an acidic medium, producing \( \text{Cr}^{3+} \) and water, along with the oxidized product of \( X \). ### Step-by-Step Solution: 1. **Identify the Reactants and Products**: The reaction is: \[ \text{Cr}_2\text{O}_7^{2-} + X + 2H^+ \rightarrow 2\text{Cr}^{3+} + H_2O + \text{oxidized product of } X ...
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CENGAGE CHEMISTRY ENGLISH-REDOX REACTIONS-Exercises (Single Correct)
  1. In the reaction K+O(2)rarrKO(2)

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  2. Which of the following is the best description of the behaviour of bro...

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  3. Cr(2)O(7)^(2-)+Xoverset(H^(o+))rarrCr^(3+)+H(2)O+ "oxidised product" o...

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  4. The oxidation state of chromium in the final product formed by the rea...

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  5. The number of moles of KMnO(4) reduced by 1 "mol of" KI in alkaline me...

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  6. In the balanced chemical reaction IO(3)^(ө)+aI^(ө)+bH^(ө)rarrcH(2)O+...

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  7. In the reaction A^(+x) + MnO(4)^() to AO(3)^() + Mn^(++) +(1)/(2)O, i...

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  8. aK(2)Cr(2)O(7)+bKCl+cH(2)SO(4) to xCrO(2)Cl(2)+yKHSO(4)+zH(2)O The a...

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  9. Oxidation number of carbon in CH(2)Cl(2) is

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  10. Excess of KI reacts with CuSO(4) solution and Na(2)SO(3) solution is a...

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  11. Calculate the oxidation number of Sulphur in H(2)SO(5). Suggest struct...

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  12. The number of peroxide bonds in perxenate ion [XeO(6)]^(4-) is

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  13. The oxidation number of Pr in Pr(6)O(11) is

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  14. In which of the following is the highest oxidation state not possible?

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  15. Which of the following statements is not correct about the given react...

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  16. Which of the following is not a disproportionation reaction ?

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  17. Which of the following is not an intramolecular redox reaction?

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  18. In the equation NO(2)^(ө)+H(2)OrarrNO(3)^(ө)+2H^(o+)+(n)(-) n stan...

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  19. Which of the following is an intermolecular redox reaction?

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  20. The oxidation state of A, B, and C in a compound are +2, +5, and -2, r...

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