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Assertion (A): Sn reacts with HCl to pro...

Assertion (A): `Sn` reacts with `HCl` to produce `H_(2)` gas.
Reason (R ): `Sn` is a better reducing agent than `H_(2)` gas.

A

If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`.

B

If both `(A)` and `(R )` are correct but `(R )` is not the correct explanation of `(A)`.

C

If `(A)` is correct but `(R )` is incorrect.

D

If `(A)` and `(R )` are incorrect.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason provided, we will analyze both statements step by step. ### Step 1: Analyze the Assertion The assertion states that "Sn reacts with HCl to produce H2 gas." - **Chemical Reaction**: The reaction can be represented as: \[ \text{Sn} + 2 \text{HCl} \rightarrow \text{SnCl}_2 + \text{H}_2 \] - In this reaction, tin (Sn) displaces hydrogen from hydrochloric acid (HCl), resulting in the formation of tin(II) chloride (SnCl2) and hydrogen gas (H2). **Conclusion for Step 1**: The assertion is correct because Sn does indeed react with HCl to produce H2 gas. ### Step 2: Analyze the Reason The reason states that "Sn is a better reducing agent than H2 gas." - **Reducing Agent**: A reducing agent is a substance that donates electrons in a chemical reaction and is oxidized in the process. To determine if Sn is a better reducing agent than H2, we need to compare their standard reduction potentials. - The standard reduction potential for the half-reaction: \[ \text{Sn}^{2+} + 2e^- \rightarrow \text{Sn} \quad (E^\circ = -0.14 \text{ V}) \] - The standard reduction potential for the half-reaction: \[ 2\text{H}^+ + 2e^- \rightarrow \text{H}_2 \quad (E^\circ = 0.00 \text{ V}) \] - Since the reduction potential of Sn is more negative than that of H2, it indicates that Sn can reduce other species (like H+) more effectively than H2 can. Therefore, Sn is indeed a better reducing agent than H2. **Conclusion for Step 2**: The reason is correct because Sn has a lower (more negative) reduction potential than H2, confirming that it is a better reducing agent. ### Final Conclusion Both the assertion and the reason are correct, and the reason provides a correct explanation for the assertion. ### Answer Both assertion (A) and reason (R) are correct, and R is the correct explanation of A.

To solve the question regarding the assertion and reason provided, we will analyze both statements step by step. ### Step 1: Analyze the Assertion The assertion states that "Sn reacts with HCl to produce H2 gas." - **Chemical Reaction**: The reaction can be represented as: \[ \text{Sn} + 2 \text{HCl} \rightarrow \text{SnCl}_2 + \text{H}_2 ...
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