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Assertion (A): PbCl(2) is more stable th...

Assertion (A): `PbCl_(2)` is more stable than `PbCl_(4)`.
Reason (R ): `PbCl_(4)` is a powerful oxidising agent.

A

If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`.

B

If both `(A)` and `(R )` are correct but `(R )` is not the correct explanation of `(A)`.

C

If `(A)` is correct but `(R )` is incorrect.

D

If `(A)` and `(R )` are incorrect.

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the assertion and reason provided in the question, we will break down the concepts related to the stability of lead(II) chloride (PbCl₂) and lead(IV) chloride (PbCl₄), as well as the properties of oxidizing agents. ### Step 1: Understanding the Assertion The assertion states that PbCl₂ is more stable than PbCl₄. - **Stability of PbCl₂ and PbCl₄**: - PbCl₂ has lead in the +2 oxidation state, which is generally more stable due to the lower oxidation state of lead compared to the +4 oxidation state in PbCl₄. - The +4 oxidation state is less stable because it is more prone to reduction, meaning it can easily lose electrons to revert to a more stable state (like PbCl₂). ### Step 2: Understanding the Reason The reason states that PbCl₄ is a powerful oxidizing agent. - **Oxidizing Agent**: - An oxidizing agent is a substance that gains electrons in a chemical reaction and, in doing so, causes another substance to be oxidized (lose electrons). - PbCl₄, being in the +4 oxidation state, is indeed a powerful oxidizing agent because it can easily accept electrons to reduce itself to PbCl₂ (where lead is in the +2 oxidation state). ### Step 3: Evaluating the Relationship between Assertion and Reason - Both the assertion (PbCl₂ is more stable than PbCl₄) and the reason (PbCl₄ is a powerful oxidizing agent) are correct statements. - However, the reason does not directly explain why PbCl₂ is more stable than PbCl₄. The stability of PbCl₂ is due to the lower oxidation state of lead, while the oxidizing nature of PbCl₄ is a separate characteristic. ### Conclusion Based on the analysis: - Assertion (A) is true: PbCl₂ is more stable than PbCl₄. - Reason (R) is true: PbCl₄ is a powerful oxidizing agent. - However, R does not provide a correct explanation for A. Thus, the correct option is that both the assertion and reason are correct, but the reason is not the correct explanation for the assertion. ### Final Answer **Both assertion and reason are correct, but reason is not the correct explanation for the assertion.**

To analyze the assertion and reason provided in the question, we will break down the concepts related to the stability of lead(II) chloride (PbCl₂) and lead(IV) chloride (PbCl₄), as well as the properties of oxidizing agents. ### Step 1: Understanding the Assertion The assertion states that PbCl₂ is more stable than PbCl₄. - **Stability of PbCl₂ and PbCl₄**: - PbCl₂ has lead in the +2 oxidation state, which is generally more stable due to the lower oxidation state of lead compared to the +4 oxidation state in PbCl₄. - The +4 oxidation state is less stable because it is more prone to reduction, meaning it can easily lose electrons to revert to a more stable state (like PbCl₂). ...
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