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Assertion (A): HNO(3) acts only as an ox...

Assertion (A): `HNO_(3)` acts only as an oxidising agent, while `HNO_(2)` acts both as an oxidising agnet and a reducing agent.
Reason (R ): The oxidation number of `N` in `HNO_(3)` is mximum.

A

If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`.

B

If both `(A)` and `(R )` are correct but `(R )` is not the correct explanation of `(A)`.

C

If `(A)` is correct but `(R )` is incorrect.

D

If `(A)` and `(R )` are incorrect.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that `HNO3` acts only as an oxidizing agent, while `HNO2` acts both as an oxidizing agent and a reducing agent. - To validate this, we need to look at the oxidation states of nitrogen in both compounds. 2. **Calculating the Oxidation State of Nitrogen**: - For `HNO3`: - The oxidation state of nitrogen (N) can be calculated as follows: - Let the oxidation state of N be x. - The overall charge of the molecule is neutral (0). - The equation is: 1 (for H) + x (for N) + 3*(-2) (for O) = 0 - This simplifies to: 1 + x - 6 = 0 → x = +5. - Therefore, the oxidation state of N in `HNO3` is +5. - For `HNO2`: - Similarly, we calculate the oxidation state of nitrogen: - Let the oxidation state of N be y. - The equation is: 1 (for H) + y (for N) + 2*(-2) (for O) = 0 - This simplifies to: 1 + y - 4 = 0 → y = +3. - Therefore, the oxidation state of N in `HNO2` is +3. 3. **Analyzing the Behavior of `HNO3`**: - Since the oxidation state of nitrogen in `HNO3` is +5 (the highest oxidation state for nitrogen), it cannot be oxidized further. Thus, `HNO3` can only act as an oxidizing agent because it can accept electrons from other substances. 4. **Analyzing the Behavior of `HNO2`**: - The oxidation state of nitrogen in `HNO2` is +3. This means it can either be oxidized to +5 (acting as a reducing agent) or reduced to a lower oxidation state (acting as an oxidizing agent). Therefore, `HNO2` can act both as an oxidizing agent and a reducing agent. 5. **Understanding the Reason (R)**: - The reason states that the oxidation number of N in `HNO3` is maximum. - This is correct, as we calculated the oxidation state of N in `HNO3` to be +5, which is indeed the maximum oxidation state for nitrogen. 6. **Conclusion**: - Both the assertion and the reason are correct. - The reason provided is a correct explanation for the assertion. ### Final Answer: Both the assertion (A) and the reason (R) are correct, and the reason is the correct explanation of the assertion.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that `HNO3` acts only as an oxidizing agent, while `HNO2` acts both as an oxidizing agent and a reducing agent. - To validate this, we need to look at the oxidation states of nitrogen in both compounds. ...
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