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Assertion (A): Sodium perxenate (Na(4)Xe...

Assertion (A): Sodium perxenate `(Na_(4)XeO_(6))` reacts with `NaF` in acidic medium to give `XeO_(3)` and `F_(2)`
Reason (R ): `XeO_(6)^(4-)` is a stronger oxidant than `F_(2)`.

A

If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`.

B

If both `(A)` and `(R )` are correct but `(R )` is not the correct explanation of `(A)`.

C

If `(A)` is correct but `(R )` is incorrect.

D

If `(A)` and `(R )` are incorrect.

Text Solution

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The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that sodium perxenate `(Na4XeO6)` reacts with `NaF` in an acidic medium to produce `XeO3` and `F2`. 1. **Chemical Reaction**: The reaction can be represented as: \[ XeO_6^{4-} + 2F^- + 6H^+ \rightarrow XeO_3 + F_2 + 3H_2O \] ### Step 2: Analyze the Oxidation States Next, we need to determine the oxidation states of xenon and fluorine in the reaction: 1. **Oxidation State of Xenon**: - In `XeO6^{4-}`, the oxidation state of Xe can be calculated as follows: \[ x + 6(-2) = -4 \implies x - 12 = -4 \implies x = +8 \] - In `XeO3`, the oxidation state of Xe is: \[ x + 3(-2) = 0 \implies x - 6 = 0 \implies x = +6 \] 2. **Oxidation State of Fluorine**: - In `F^-`, the oxidation state is -1. - In `F2`, the oxidation state is 0. ### Step 3: Determine Oxidation and Reduction Now, we can identify which species is oxidized and which is reduced: 1. **Reduction**: - Xenon is reduced from +8 in `XeO6^{4-}` to +6 in `XeO3`. 2. **Oxidation**: - Fluorine is oxidized from -1 in `F^-` to 0 in `F2`. ### Step 4: Compare Oxidizing Strength The reason states that `XeO6^{4-}` is a stronger oxidant than `F2`. 1. **Conclusion**: - Since `XeO6^{4-}` is reduced (gaining electrons) and `F^-` is oxidized (losing electrons), it confirms that `XeO6^{4-}` acts as a stronger oxidizing agent than `F2`. ### Final Conclusion Both the assertion and the reason are correct, and the reason correctly explains the assertion. ### Answer: Both the assertion and reason are correct, and the reason is the correct explanation of the assertion.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that sodium perxenate `(Na4XeO6)` reacts with `NaF` in an acidic medium to produce `XeO3` and `F2`. 1. **Chemical Reaction**: The reaction can be represented as: \[ ...
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