Home
Class 11
CHEMISTRY
The bond energies of C=C and C-C at 298 ...

The bond energies of `C=C` and `C-C` at `298 K` are `590` and `331 kJ mol^(-1)`, respectively. The enthalpy of polymerisation per mole of ethaylene is

A

`-70 kJ`

B

`-72 kJ`

C

`72 kJ`

D

`-68 kJ`

Text Solution

AI Generated Solution

To find the enthalpy of polymerization per mole of ethylene, we will use the bond energies provided and apply the concept of bond energy in the context of a polymerization reaction. ### Step-by-Step Solution: 1. **Identify the Reaction**: In the polymerization of ethylene (C₂H₄), the double bond (C=C) in ethylene converts to single bonds (C-C) in the polymer. The reaction can be represented as: \[ n \text{ C}_2\text{H}_4 \rightarrow \text{(C-C)}_n ...
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercise|1 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 6.1|26 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

The polymerisation of ethylene to linear polyethylene is represented by the reaction nCH_(2)=CH_(2)rarr(-CH_(2)-CH_(2)-)_(n) When n has a large integral value. Given theat the average enthalpies of bond dissociation for C=C and C-C at 298K are +590 and +331kJ mol^(-1) respectively, calculate the enthalpy of polymerisation per mole of ethylene at 298K .

The polymerisation of propene to linear polypropene is represented by the reaction where n has intergral value, the average enthalpies of bond dissociation for (C =C) and (C -C) at 298K are +509 and +331 kJ mol^(-1) , respectively. the enthalpy of polymerisation is -360 kJ . Find the value of n .

Calculate the resonance energy of isoprene (C_(5)H_(8)) from the data given. Standard Heats of combustion of isoprene, carbon and hydrogen are -3186, -393.5 , and -285.83 kJ mol^(-1) , respectively. Bond energies of C=C, C-C, C-H and H-H bonds are 615, 348, 413 and 435.8 kJ mol^(-1) respectively. Standard heat of sublimation of graphite is 718.3 kJ mol^(-1) .

The bond energies of H - H and I - I bonds are 435 kJ mol^-1 and 150 kJ mol^-1 respectively. If DeltaH_f^o for HI is 26.5 kJ mol^-1 then bond enthalpy of H-I bond is

The enthalpies of combustion of carbon and carbon monoxide are -393.5 and -283 kJ mol^(-1) respectively. The enthaly of formation of carbon monoxide per mole is :

The standard molar enthalpies of formation of cyclohexane and benzene at 25^@C are - 156 and +49 KJ mol^(-1) respectively. The standard enthalpy of hydrogenation of cyclo hexene at 25^@C " is" -116 "KJ mol" ^(-1) . Use this data to estimate the magnitude of the resonance energy of benzene.

In C_(2)H_(4) energies of formation of (C=C) and (C-C) are -145 kJ/mol and -80kJ/mol respectively. What is the enthalpy change w hen ethylene polymerises to form polythene?

The heat of dissociation of benzene in isolated gaseous atoms is 5335 kJ/mol . The bond enthalpies C-C, C = C and C - H bonds are 347.3, 615 and 416.2 kJ respectively. Magnitude of resonance energy of benzene is

Given the bond energies of H - H and Cl - Cl are 430 kJ mol^(-1) and 240 kJ mol^(-1) , respectively, and Delta_(f) H^(@) for HCl is - 90 kJ mol^(-1) . Bond enthalpy of HCl is

The Bond energy of C=C, C-C, C-H and H-H are 147, 83, 99 and 104 kcal/mol respectively then calculate heat of hydrogen of ethene.

CENGAGE CHEMISTRY ENGLISH-THERMODYNAMICS-Archives (Subjective)
  1. The bond energies of C=C and C-C at 298 K are 590 and 331 kJ mol^(-1),...

    Text Solution

    |

  2. The enthalpies for the following reactions (DeltaH^(Theta)) at 25^(@)C...

    Text Solution

    |

  3. The standared enthalpies of formation at 298K for C C1(g), H(2)O(g), C...

    Text Solution

    |

  4. Given that: i. C(s) + O(2)(g) rarr CO(2)(g) , DeltaH =- 94.05 kcal ...

    Text Solution

    |

  5. The following statement is true only under some specific conditions. W...

    Text Solution

    |

  6. The bond dissociation energies of gaseous H(2),Cl(2), and HCl are 100,...

    Text Solution

    |

  7. The standard molar heat of formation of ethane, carbon dioxide and wat...

    Text Solution

    |

  8. An intimate mixture of ferric oxide and aluminium is used as solid fue...

    Text Solution

    |

  9. The enthalpy of combustion of H(2), cyclohexene (C(6)H(10)) and cycloh...

    Text Solution

    |

  10. CsOH +HCI rarr CsCI +H(2)O, DeltaH =- 13.4 kcal mol^(-1)……….(i) CsOH...

    Text Solution

    |

  11. Determine enthalpy change for, C(3)H(8(g))+H(2(g))rarr C(2)H(6(g))+C...

    Text Solution

    |

  12. Compute the heat of formation of liquid methyl alcohol in kilojoule pe...

    Text Solution

    |

  13. From the following data, calculate the enthalpy change for the combust...

    Text Solution

    |

  14. The standard heat of formation values of SF(6)(g), S(g), and F(g) are ...

    Text Solution

    |

  15. Show that the reaction CO(g) +(1//2)O(2)(g) rarr CO(2)(g) at 300K ...

    Text Solution

    |

  16. A sample of argon gas at 1atm pressure and 27^(@)C expands reversibly ...

    Text Solution

    |

  17. Determine the enthalpy of formation of B(2)H(6)(g) in kJ/mol of the fo...

    Text Solution

    |

  18. The standart potential of the following cell is 0.23 at 15^(@)C and 0....

    Text Solution

    |

  19. When 1pentyne (A) is treated with 4N alcoholic KOH at 175^(@)C, it is ...

    Text Solution

    |

  20. Two moles of a perfect gas undergo the following processes: a. A rev...

    Text Solution

    |

  21. C(v) values of He is always (3R)/(2) but C(v) values of H(2) is (3R)/(...

    Text Solution

    |