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Quick lime: (CaO)is produced bu heating ...

Quick lime: `(CaO)`is produced bu heating limestone `(CaCO_(3))` to derive off `CO_(2)` gas.
`CaCO_(3) (s) rarr CaO(s) +CO_(2)(g), Delta_(r)H^(Theta) = 180 k J mol^(-1), Delta_(r)S^(Theta) = 150 J K^(-1)`
Assuming that variation fo enthalpy change and entropy change with temperature to be negligible, which of the following is correct?

A

Decomposition of `CaCO_(3)(s)` is always nonspontaneous.

B

Decomposition of `CaCO_(3)(s)` become spontaneous when temperature is less than `27^(@)C`.

C

Decomposition of `CaCO_(3)(s)` become spontaneous when temperature is greater than `1200^(@)C`.

D

Decomposition of `CaCO_(3)(s)` become spontaneous when temperature is greater than `927^(@)C`.

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To solve the problem regarding the spontaneity of the reaction where quick lime (CaO) is produced from limestone (CaCO₃), we need to analyze the given thermodynamic data and apply the Gibbs free energy equation. ### Step-by-Step Solution: 1. **Identify the Reaction and Given Data:** The reaction is: \[ \text{CaCO}_3 (s) \rightarrow \text{CaO} (s) + \text{CO}_2 (g) ...
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