Home
Class 11
CHEMISTRY
In a fuel cell, methanol if used as fuel...

In a fuel cell, methanol if used as fuel and oxygen gas is used as an oxidiser. The reaction is
`CH_(3)OH(l) +(3)/(2)O_(2)(g)rarrCO_(2)(g)+2H_(2)O(l)`
Calculated standard Gibbs free enegry change for the reaction that can be converted into electrical work. If standard enthalpy of combustion for methanol is `-702 kJ mol^(-1)`, calculate the efficiency of conversion of Gibbs energy into useful work.
`Delta_(f)G^(Theta)` for `CO_(2),H_(2)O, CH_(3)OH,O_(2)` is `-394.00, -237.00,-166.00`and `0 kJ mol^(-1)` respectively.

Text Solution

AI Generated Solution

To solve the problem, we need to calculate the standard Gibbs free energy change (ΔG°) for the given reaction and then determine the efficiency of the conversion of Gibbs energy into useful work. Here are the steps to arrive at the solution: ### Step 1: Write the Balanced Reaction The balanced reaction for the combustion of methanol is: \[ \text{CH}_3\text{OH}(l) + \frac{3}{2} \text{O}_2(g) \rightarrow \text{CO}_2(g) + 2 \text{H}_2\text{O}(l) \] ### Step 2: Identify the Standard Gibbs Free Energy Values We are given the standard Gibbs free energy of formation (ΔG°f) for the substances involved: ...
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercise|1 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 6.1|26 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

In a fuel cell methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is : CH_(3)OH_((l))+(3)/(2)O_(2(g))rarr CO_2((g))+2H_(2)O_((l)) At 298K standard Gibb's energies of formation for CH_(3)OH(l), H_(2)O(l) and CO_(2)(g) are -166.2,-237.2 and -394.4kJ mol^(-1) respectively. If standard enthalpy of combustion of methanol is -726kJ mol^(-1) , efficiency of the fuel cell will be :

In a fuel cell methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is : CH_(3)OH_((l))+(3)/(2)O_(2(g))rarr CO_2((g))+2H_(2)O_((l)) At 298K standard Gibb's energies of formation for CH_(3)OH(l), H_(2)O(l) and CO_(2)(g) are -166.2,-237.2 and -394.4kJ mol^(-1) respectively. If standard enthalpy of combustion of methanol is -726kJ mol^(-1) , efficiency of the fuel cell will be :

In a fuel cell methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is : CH_(3)OH_((l))+(3)/(2)O_(2(g))rarr CO_2((g))+2H_(2)O_((l)) At 298K standard Gibb's energies of formation for CH_(3)OH(l), H_(2)O(l) and CO_(2)(g) are -166.2,-237.2 and -394.4kJ mol^(-1) respectively. If standard enthalpy of combustion of methanol is -726kJ mol^(-1) , efficiency of the fuel cell will be :

In a fuel cell methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is : CH_(3)OH_((l))+(3)/(2)O_(2(g))rarr CO_2((g))+2H_(2)O_((l)) At 298K standard Gibb's energies of formation for CH_(3)OH(l), H_(2)O(l) and CO_(2)(g) are -166.2,-237.2 and -394.4kJ mol^(-1) respectively. If standard enthalpy of combustion of methanol is -726kJ mol^(-1) , efficiency of the fuel cell will be :

For the reaction C_2H_(5)OH(l) + 3 O_(2)(g) rightarrow 2CO_(2)(g) + 3 H_(2)O(l) , which one is true ?

For the reaction : 4Al+ 3O_(2) + 6H_(2)O+ 4OH^(-) rightarrow4A1(OH)_(4)^(-) E^(@)_(cell) = 2.73V . Standard Gibb's free energy change for the reaction is :

At 298K , the enthalpy of combustion of CH_(4) corresponds to the reaction CH_(4)(g) +2O_(2)(g) rarr CO_(2)(g)+2H_(2)O(g)

The equilibrium constant for the reaction: CH_(3)COOH(l) +C_(2)H_(5)OH(l) hArr CH_(3)COOC_(2)H_(5)(l)+H_(2)O(l) has been found to be equal to 4 at 25^(@)C . Calculate the free energy change for the reaction.

The value of enthalpy change ( DeltaH ) for the reaction C_2H_5OH(l) + 3O_2(g) to 2CO_2(g) +3H_2O(l) at 27^@C is -1366.5 kJ mol^(-1) . The value of internal energy change for the above reaction at this temperature will be

Diborane is a potential rocket fuel that undergoes combustion according to the reaction, B_(2)H_(6)(g) +3O_(2)(g) rarr B_(2)O_(3)(g) +3H_(2)O(g) From the following data, calculate the enthalpy change for the combustion of diborane:

CENGAGE CHEMISTRY ENGLISH-THERMODYNAMICS-Archives (Subjective)
  1. In a fuel cell, methanol if used as fuel and oxygen gas is used as an ...

    Text Solution

    |

  2. The enthalpies for the following reactions (DeltaH^(Theta)) at 25^(@)C...

    Text Solution

    |

  3. The standared enthalpies of formation at 298K for C C1(g), H(2)O(g), C...

    Text Solution

    |

  4. Given that: i. C(s) + O(2)(g) rarr CO(2)(g) , DeltaH =- 94.05 kcal ...

    Text Solution

    |

  5. The following statement is true only under some specific conditions. W...

    Text Solution

    |

  6. The bond dissociation energies of gaseous H(2),Cl(2), and HCl are 100,...

    Text Solution

    |

  7. The standard molar heat of formation of ethane, carbon dioxide and wat...

    Text Solution

    |

  8. An intimate mixture of ferric oxide and aluminium is used as solid fue...

    Text Solution

    |

  9. The enthalpy of combustion of H(2), cyclohexene (C(6)H(10)) and cycloh...

    Text Solution

    |

  10. CsOH +HCI rarr CsCI +H(2)O, DeltaH =- 13.4 kcal mol^(-1)……….(i) CsOH...

    Text Solution

    |

  11. Determine enthalpy change for, C(3)H(8(g))+H(2(g))rarr C(2)H(6(g))+C...

    Text Solution

    |

  12. Compute the heat of formation of liquid methyl alcohol in kilojoule pe...

    Text Solution

    |

  13. From the following data, calculate the enthalpy change for the combust...

    Text Solution

    |

  14. The standard heat of formation values of SF(6)(g), S(g), and F(g) are ...

    Text Solution

    |

  15. Show that the reaction CO(g) +(1//2)O(2)(g) rarr CO(2)(g) at 300K ...

    Text Solution

    |

  16. A sample of argon gas at 1atm pressure and 27^(@)C expands reversibly ...

    Text Solution

    |

  17. Determine the enthalpy of formation of B(2)H(6)(g) in kJ/mol of the fo...

    Text Solution

    |

  18. The standart potential of the following cell is 0.23 at 15^(@)C and 0....

    Text Solution

    |

  19. When 1pentyne (A) is treated with 4N alcoholic KOH at 175^(@)C, it is ...

    Text Solution

    |

  20. Two moles of a perfect gas undergo the following processes: a. A rev...

    Text Solution

    |

  21. C(v) values of He is always (3R)/(2) but C(v) values of H(2) is (3R)/(...

    Text Solution

    |