Home
Class 11
CHEMISTRY
For the reaction: CO(g) +H(2)O(g) hArr...

For the reaction:
`CO(g) +H_(2)O(g) hArr CO_(2)(g) +H_(2)(g)`
`(Delta_(r)H)_(300K) = - 41.2 kJ mol^(-1)`
`(Delta_(r)H)_(1200K) =- 33.0 kJ mol^(-1)`
`(Delta_(r)S)_(300K) = - 4.2 xx 10^(-2) kJ mol^(-1)`
`(Delta_(r)S)_(1200K) =- 3.0 xx10^(-2) kJ mol^(-1)`
Predict the direction of spontaneity of the reaction at `300K` and `1200K`. also calculated `log_(10)K_(p)` at `300K` and `1200K`.

Text Solution

AI Generated Solution

To solve the problem, we need to determine the spontaneity of the reaction at two different temperatures (300 K and 1200 K) and calculate the logarithm of the equilibrium constant (log Kp) at these temperatures. We'll use the Gibbs free energy equation: \[ \Delta G = \Delta H - T \Delta S \] ### Step 1: Calculate ΔG at 300 K ...
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercise|1 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 6.1|26 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

The standard enthalpy and entropy changes for the reaction in equilibrium for the forward direction are given below: CO(g) +H_(2)O(g) hArr CO_(2)(g) +H_(2)(g) DeltaH^(Theta)underset(300K). =- 41.16 kJ mol^(-1) DeltaS^(Theta)underset(300K). =- 4.24 xx 10^(-2) kJ mol^(-1) DeltaH^(Theta)underset(1200K). =- 32.93 kJ mol^(-1) DeltaH^(Theta)underset(1200K). =- 2.96 xx 10^(-2) kJ mol^(-1) Calculate K_(p) at each temperature and predict the direction of reaction at 300K and 1200k , when P_(CO) = P_(CO_(2)) =P_(H_(2)) = P_(H_(2)O) =1 atm at initial state.

For the reaction : C_(2)H_(5)OH(l)+3O_(2)(g)rarr2CO_(2)(g)+3H_(2)O(g) if Delta U^(@)= -1373 kJ mol^(-1) at 298 K . Calculate Delta H^(@)

DeltaG° for the following reaction: I_2(s) + H_2S(g) rarr 2HI(g) + S(s) at 298 K is, Given that Delta_fG°HI(g) = 1.8 kJ mol^-1 . Delta_fG°H_2S(g) = 33.8 kJ mol^-1 .

Calculate equilibrium constant for the reaction: 2SO_(2)(g) +O_(2)(g) hArr 2SO_(3)(g) at 25^(@)C Given: Delta_(f)G^(Theta) SO_(3)(g) = - 371.1 kJ mol^(-1) , Delta_(f)G^(Theta)SO_(2)(g) =- 300.2 kJ mol^(-1) and R = 8.31 J K^(-1) mol^(-1)

Calculate Delta_(r)S_("sys")^(@) for the following reaction at 373 K: CO(g) + H_(2)O(g) to CO_(2)(g) + H_(2)(g) Delta_(r)H^(@) = -4.1 xx 10^(4) J, Delta_(r)S^(@)("unv") = 56 J//K

For the equilibrium reaction: 2H_(2)(g) +O_(2)(g) hArr 2H_(2)O(l) at 298 K DeltaG^(Theta) = - 474.78 kJ mol^(-1) . Calculate log K for it. (R = 8.314 J K^(-1)mol^(-1)) .

Predict whether the following reaction is possible or not at 300k . 2CuO(s) rarr Cu_(2)O(s) +1//2O_(2)(g) DeltaH =- 144.6 kJ mol^(-1), DeltaS = 0.116 kJ mol^(-1)

The temperature at which the given reaction is at equilibrium Ag_(2)O_(s) rightarrow 2Ag(s) + 1/2 O_(2)(g) Delta H = 40.5 kJ mol^(-1) and DeltaS= 0.086 k J mol^(-1) K^(-1)

For a reversible reaction A hArr B . Find (log_(10)K)/(10) at 2727^(@) C temperature Given Delta_(r)H^(0) = - 54.07 kJ mol^(-1) Delta_(r)S^(0) = 10 JK^(-1) R = 8.314 JK^(-1) mol^(-1)

For the reaction at 300 K A(g)hArrV(g)+S(g) Delta_(r)H^(@)=-30kJ//mol, Delta_(r)S^(@)=-0.1kJK^(-1).mol^(-1) What is the value of equilibrium constant ?

CENGAGE CHEMISTRY ENGLISH-THERMODYNAMICS-Archives (Subjective)
  1. For the reaction: CO(g) +H(2)O(g) hArr CO(2)(g) +H(2)(g) (Delta(r)...

    Text Solution

    |

  2. The enthalpies for the following reactions (DeltaH^(Theta)) at 25^(@)C...

    Text Solution

    |

  3. The standared enthalpies of formation at 298K for C C1(g), H(2)O(g), C...

    Text Solution

    |

  4. Given that: i. C(s) + O(2)(g) rarr CO(2)(g) , DeltaH =- 94.05 kcal ...

    Text Solution

    |

  5. The following statement is true only under some specific conditions. W...

    Text Solution

    |

  6. The bond dissociation energies of gaseous H(2),Cl(2), and HCl are 100,...

    Text Solution

    |

  7. The standard molar heat of formation of ethane, carbon dioxide and wat...

    Text Solution

    |

  8. An intimate mixture of ferric oxide and aluminium is used as solid fue...

    Text Solution

    |

  9. The enthalpy of combustion of H(2), cyclohexene (C(6)H(10)) and cycloh...

    Text Solution

    |

  10. CsOH +HCI rarr CsCI +H(2)O, DeltaH =- 13.4 kcal mol^(-1)……….(i) CsOH...

    Text Solution

    |

  11. Determine enthalpy change for, C(3)H(8(g))+H(2(g))rarr C(2)H(6(g))+C...

    Text Solution

    |

  12. Compute the heat of formation of liquid methyl alcohol in kilojoule pe...

    Text Solution

    |

  13. From the following data, calculate the enthalpy change for the combust...

    Text Solution

    |

  14. The standard heat of formation values of SF(6)(g), S(g), and F(g) are ...

    Text Solution

    |

  15. Show that the reaction CO(g) +(1//2)O(2)(g) rarr CO(2)(g) at 300K ...

    Text Solution

    |

  16. A sample of argon gas at 1atm pressure and 27^(@)C expands reversibly ...

    Text Solution

    |

  17. Determine the enthalpy of formation of B(2)H(6)(g) in kJ/mol of the fo...

    Text Solution

    |

  18. The standart potential of the following cell is 0.23 at 15^(@)C and 0....

    Text Solution

    |

  19. When 1pentyne (A) is treated with 4N alcoholic KOH at 175^(@)C, it is ...

    Text Solution

    |

  20. Two moles of a perfect gas undergo the following processes: a. A rev...

    Text Solution

    |

  21. C(v) values of He is always (3R)/(2) but C(v) values of H(2) is (3R)/(...

    Text Solution

    |