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In a reaction at equilibrium, X moles of...

In a reaction at equilibrium, X moles of the reactant A decomposes to give `1` mole each of C and D. It has been found that the fraction of A decomposed at equilibrium is independent of initial concentration of A. Calculate X.

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To solve the problem step by step, let's break down the information given and derive the solution systematically. ### Step 1: Write the Reaction The decomposition of reactant A can be represented as: \[ A \rightarrow C + D \] where \( x \) moles of A decompose to give 1 mole each of C and D. ### Step 2: Define Initial and Equilibrium Concentrations Let: - The initial concentration of A be \( C \) (in moles). - The fraction of A that decomposes be \( \alpha \). At equilibrium: - The concentration of A will be \( C(1 - \alpha) \). - The concentration of C will be \( \frac{C\alpha}{x} \) (since 1 mole of C is produced for every \( x \) moles of A). - The concentration of D will also be \( \frac{C\alpha}{x} \). ### Step 3: Write the Expression for the Equilibrium Constant (\( K_c \)) The equilibrium constant expression for the reaction is given by: \[ K_c = \frac{[C][D]}{[A]^x} \] Substituting the equilibrium concentrations: \[ K_c = \frac{\left(\frac{C\alpha}{x}\right) \left(\frac{C\alpha}{x}\right)}{(C(1 - \alpha))^x} \] This simplifies to: \[ K_c = \frac{\frac{C^2\alpha^2}{x^2}}{C^x(1 - \alpha)^x} \] \[ K_c = \frac{C^2\alpha^2}{x^2 C^x (1 - \alpha)^x} \] \[ K_c = \frac{\alpha^2}{x^2 (1 - \alpha)^x} \] ### Step 4: Analyze the Independence from Initial Concentration The problem states that the fraction of A decomposed at equilibrium is independent of the initial concentration of A. This implies that the equilibrium constant \( K_c \) must not depend on \( C \). To achieve this, we need to choose \( x \) such that the concentration term cancels out. ### Step 5: Determine the Value of \( x \) To make \( K_c \) independent of the concentration \( C \), we can set \( x = 2 \). Substituting \( x = 2 \) into the equilibrium expression: \[ K_c = \frac{\alpha^2}{2^2 (1 - \alpha)^2} \] \[ K_c = \frac{\alpha^2}{4(1 - \alpha)^2} \] This expression is now independent of \( C \). ### Conclusion Thus, the value of \( x \) is: \[ \boxed{2} \]

To solve the problem step by step, let's break down the information given and derive the solution systematically. ### Step 1: Write the Reaction The decomposition of reactant A can be represented as: \[ A \rightarrow C + D \] where \( x \) moles of A decompose to give 1 mole each of C and D. ...
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