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K(p) and K(c) are inter related as K(p...

`K_(p)` and `K_(c)` are inter related as
`K_(p)=K_(c)(RT)^(Deltan)`
Answer the following questions:
The unit of equilibrium constant for
`H_(2)(g)+I_(2)(g) hArr 2HI(g)`

A

mol `L^(-2)`

B

`mol^(2) L^(-2)`

C

`L mol^(-2)`

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To find the unit of the equilibrium constant for the reaction: \[ H_2(g) + I_2(g) \rightleftharpoons 2HI(g) \] we will follow these steps: ### Step 1: Identify the reaction and count moles The reaction involves: - Reactants: \( H_2 \) and \( I_2 \) (both are gases) - Products: \( 2HI \) (gas) ### Step 2: Calculate the change in moles (Δn) The change in moles (Δn) is calculated as: \[ \Delta n = \text{(moles of gaseous products)} - \text{(moles of gaseous reactants)} \] From the reaction: - Moles of gaseous products = 2 (from \( 2HI \)) - Moles of gaseous reactants = 1 (from \( H_2 \)) + 1 (from \( I_2 \)) = 2 Thus, \[ \Delta n = 2 - 2 = 0 \] ### Step 3: Determine the unit of \( K_c \) The unit of the equilibrium constant \( K_c \) is given by: \[ K_c = \frac{[\text{products}]}{[\text{reactants}]} \] For our reaction, the unit of \( K_c \) can be expressed as: \[ K_c = \frac{[HI]^2}{[H_2][I_2]} \] The concentration units for each component are in moles per liter (mol/L). Therefore, substituting the units: \[ K_c = \frac{(mol/L)^2}{(mol/L)(mol/L)} = \frac{(mol/L)^2}{(mol/L)^2} = 1 \] ### Step 4: Conclusion Since \( \Delta n = 0 \), we find that: \[ K_c = (mol/L)^0 = 1 \] Thus, the unit of the equilibrium constant \( K_c \) for the given reaction is dimensionless (no units).
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