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Consider the following reactions: i. C...

Consider the following reactions:
i. `CO(g)+H_(2)O(g) hArr CO_(2)(g)+H_(2)(g), K_(1)`
ii. `CH_(4)(g)+H_(2)O(g) hArr CO(g)+3H_(2)(g), K_(2)`
iii. `CH_(4)(g)+2H_(2)O(g) hArr CO_(2)(g)+4H_(2)(g), K_(3)`
Which of the following is/are incorrect?

A

`K_(3)=K_(1)//K_(2)`

B

`K_(3)=K_(1)^(2)//K_(2)^(3)`

C

`K_(3)=K_(1)xxK_(2)`

D

`K_(3)=K_(1)sqrt(K_(2))`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given chemical reactions and their corresponding equilibrium constants. Let's break it down step by step. ### Step 1: Write down the reactions and their equilibrium constants 1. **Reaction 1**: \[ \text{CO}(g) + \text{H}_2\text{O}(g) \rightleftharpoons \text{CO}_2(g) + \text{H}_2(g), \quad K_1 \] 2. **Reaction 2**: \[ \text{CH}_4(g) + \text{H}_2\text{O}(g) \rightleftharpoons \text{CO}(g) + 3\text{H}_2(g), \quad K_2 \] 3. **Reaction 3**: \[ \text{CH}_4(g) + 2\text{H}_2\text{O}(g) \rightleftharpoons \text{CO}_2(g) + 4\text{H}_2(g), \quad K_3 \] ### Step 2: Combine the first two reactions To find a relationship between the equilibrium constants, we can add Reaction 1 and Reaction 2. - **Adding Reaction 1 and Reaction 2**: \[ \text{CO}(g) + \text{H}_2\text{O}(g) + \text{CH}_4(g) + \text{H}_2\text{O}(g) \rightleftharpoons \text{CO}_2(g) + \text{H}_2(g) + \text{CO}(g) + 3\text{H}_2(g) \] - Simplifying this, we cancel out CO on both sides: \[ \text{CH}_4(g) + 2\text{H}_2\text{O}(g) \rightleftharpoons \text{CO}_2(g) + 4\text{H}_2(g) \] ### Step 3: Relate the equilibrium constants According to the principle of equilibrium constants: - When two reactions are added, their equilibrium constants multiply. Thus, we have: \[ K_3 = K_1 \times K_2 \] ### Step 4: Identify incorrect statements Now we need to determine which statements regarding the equilibrium constants are incorrect. Based on our derivation: - The correct relationship is \( K_3 = K_1 \times K_2 \). - Any statement claiming otherwise (like \( K_1 \) or \( K_2 \) being equal to \( K_3 \) or any other incorrect relationships) would be incorrect. ### Conclusion The incorrect statements among the options provided would be those that do not align with \( K_3 = K_1 \times K_2 \).

To solve the problem, we need to analyze the given chemical reactions and their corresponding equilibrium constants. Let's break it down step by step. ### Step 1: Write down the reactions and their equilibrium constants 1. **Reaction 1**: \[ \text{CO}(g) + \text{H}_2\text{O}(g) \rightleftharpoons \text{CO}_2(g) + \text{H}_2(g), \quad K_1 \] 2. **Reaction 2**: \[ \text{CH}_4(g) + \text{H}_2\text{O}(g) \rightleftharpoons \text{CO}(g) + 3\text{H}_2(g), \quad K_2 \] ...
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For the following three reactions (i),(ii) and (iii) equlibrium constant are given. (i) CO(g) +H_2O (g) hArr CO_2( g)+ H_2(g) ,K_1 (ii) CH_4(g) + H_2O (g) hArr CO(g) +3H_2(g) , K_2 (iii) CH_4(g) + 2H_2O(g) hArr CO_2(g) +4H_2(g) , K_3 Which of the following relations is correct ?

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Consider the reaction :- 2CO(g)+2H_(2)O_((g))hArr2CO_(2(g))+2H_(2(g))eq.const=K_(1) CH_(4(g))+H_(2)O_((g))hArrCO_((g))+3H_(2(g)),eq.const=K_(2) CH_(4(g))+2H_(2)O_((g))hArrCO_(2(g))+4H_(2(g)),eq.const=K_(3) Which of the following relation is correct ?

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