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The equilibrium constant for a reaction ...

The equilibrium constant for a reaction
`A+2B hArr 2C` is `40`. The equilibrium constant for reaction `C hArr B+1//2 A` is

A

`1//40`

B

`(1//40)^(1//2)`

C

`(1//40)^(2)`

D

`40`

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The correct Answer is:
To solve the problem, we need to find the equilibrium constant for the reaction: \[ C \rightleftharpoons B + \frac{1}{2} A \] given that the equilibrium constant for the reaction: \[ A + 2B \rightleftharpoons 2C \] is \( K_1 = 40 \). ### Step-by-Step Solution: 1. **Write the equilibrium expression for the first reaction:** The equilibrium constant \( K_1 \) for the reaction \( A + 2B \rightleftharpoons 2C \) is given by: \[ K_1 = \frac{[C]^2}{[A][B]^2} \] Given \( K_1 = 40 \), we have: \[ \frac{[C]^2}{[A][B]^2} = 40 \] 2. **Write the equilibrium expression for the second reaction:** For the reaction \( C \rightleftharpoons B + \frac{1}{2} A \), the equilibrium constant \( K_2 \) can be expressed as: \[ K_2 = \frac{[B]^{1}[A]^{\frac{1}{2}}}{[C]^{1}} = \frac{[B] \sqrt{[A]}}{[C]} \] 3. **Relate \( K_2 \) to \( K_1 \):** To find \( K_2 \), we can manipulate the first reaction. The second reaction is essentially the reverse of the first reaction, but with different stoichiometry. To find \( K_2 \), we can use the relationship between the equilibrium constants when reactions are reversed or modified: - Reversing a reaction inverts the equilibrium constant. - Halving the coefficients of a balanced equation takes the square root of the equilibrium constant. Since the first reaction is: \[ A + 2B \rightleftharpoons 2C \] and we want to find \( C \rightleftharpoons B + \frac{1}{2} A \), we first reverse the first reaction: \[ 2C \rightleftharpoons A + 2B \] The equilibrium constant for this reversed reaction is: \[ K' = \frac{1}{K_1} = \frac{1}{40} \] 4. **Adjust for stoichiometry:** Now, we need to adjust for the fact that the coefficients in the new reaction are halved: \[ C \rightleftharpoons B + \frac{1}{2} A \] Therefore, we take the square root of \( K' \): \[ K_2 = \sqrt{K'} = \sqrt{\frac{1}{40}} = \frac{1}{\sqrt{40}} = \frac{1}{\sqrt{40}} = \frac{1}{\sqrt{40}} \approx 0.158 \] ### Final Answer: Thus, the equilibrium constant for the reaction \( C \rightleftharpoons B + \frac{1}{2} A \) is: \[ K_2 = \frac{1}{\sqrt{40}} \]

To solve the problem, we need to find the equilibrium constant for the reaction: \[ C \rightleftharpoons B + \frac{1}{2} A \] given that the equilibrium constant for the reaction: \[ A + 2B \rightleftharpoons 2C \] ...
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL EQUILIBRIUM-Exercises (Single Correct)
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  2. The solubility of CO(2) in water increases with

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  3. The equilibrium constant for a reaction A+2B hArr 2C is 40. The equi...

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  4. Inert gas has been added to the following equilibrium system at consta...

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  5. The equilibrium constant K for the reaction 2HI(g) hArr H(2)(g)+I(2)(g...

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  7. For the reaction N(2)O(4)(g)hArr2NO(2)(g), the degree of dissociation ...

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  8. 4 mol of carbon dioxide was heated in 1 dm^(3) vessel under conditions...

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  9. 1 mol of N(2) is mixed with 3 mol of H(2) in a litre container. If 50%...

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  10. The equilibrium constant of a reaction is 300, if the volume of the re...

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  11. For reaction : H(2)(h)+I(2)(g) hArr 2HI(g) at certain temperature, the...

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  12. The system PCl(5)(g) hArr PCl(3)(g)+Cl(2)(g) attains equilibrium. If t...

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  13. XY(2) dissociates XY(2)(g) hArr XY(g)+Y(g). When the initial pressure ...

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  14. Consider the reaction A(g)+B(g) hArr C(g)+D(g) Which occurs in one...

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  15. For the equilibrium system 2HX(g) hArr H(2)(g)+X(2)(g) the equilib...

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  16. In alkaline solution, the following equilibria exist a. S^(2-)+S rar...

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  17. Given the equilibrium constants HgCl^(o+)+Cl^(ɵ) rarr HgCl(2), K(1)=...

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  18. When the reaction, 2NO(2)(g) hArr N(2)O(4)(g) reaches equilibrium at 2...

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  19. The vapour density of mixture consisting of NO2 and N2O4 is 38.3 at 26...

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  20. In the problem number 21, the number of mole of N(2)O(4) in 100 g of t...

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