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M(2)SO(4) (M^(o+) is a monovalent metal ...

`M_(2)SO_(4) (M^(o+)` is a monovalent metal ion) has a `K_(sp)` of `3.2 xx 10^(-6)`at `298 K`. The maximum concentration of `SO_(4)^(2-)` ion that could be attained in a saturated solution of this solid at `298 K` is

A

`3 xx 10^(-3)M`

B

`7 xx 10^(-2)M`

C

`2.89 xx 10^(-4)M`

D

`2xx10^(-2)M`

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The correct Answer is:
To find the maximum concentration of \( \text{SO}_4^{2-} \) ions in a saturated solution of \( \text{M}_2\text{SO}_4 \) at 298 K, we can follow these steps: ### Step-by-Step Solution: 1. **Write the Dissociation Reaction**: The dissociation of \( \text{M}_2\text{SO}_4 \) in water can be represented as: \[ \text{M}_2\text{SO}_4 (s) \rightleftharpoons 2 \text{M}^+ (aq) + \text{SO}_4^{2-} (aq) \] 2. **Define Solubility**: Let the solubility of \( \text{M}_2\text{SO}_4 \) be \( S \) mol/L. According to the stoichiometry of the dissociation: - The concentration of \( \text{M}^+ \) ions will be \( 2S \). - The concentration of \( \text{SO}_4^{2-} \) ions will be \( S \). 3. **Write the Expression for \( K_{sp} \)**: The solubility product constant \( K_{sp} \) is given by: \[ K_{sp} = [\text{M}^+]^2 [\text{SO}_4^{2-}] \] Substituting the concentrations in terms of \( S \): \[ K_{sp} = (2S)^2 \cdot (S) = 4S^3 \] 4. **Substitute the Given \( K_{sp} \)**: We know that \( K_{sp} = 3.2 \times 10^{-6} \). Therefore, we can set up the equation: \[ 4S^3 = 3.2 \times 10^{-6} \] 5. **Solve for \( S^3 \)**: Rearranging the equation gives: \[ S^3 = \frac{3.2 \times 10^{-6}}{4} = 0.8 \times 10^{-6} \] 6. **Calculate \( S \)**: To find \( S \), we take the cube root: \[ S = \sqrt[3]{0.8 \times 10^{-6}} \] 7. **Final Calculation**: Evaluating the cube root: \[ S \approx 2 \times 10^{-2} \text{ mol/L} \] ### Conclusion: Thus, the maximum concentration of \( \text{SO}_4^{2-} \) ions that could be attained in a saturated solution of \( \text{M}_2\text{SO}_4 \) at 298 K is: \[ \boxed{2 \times 10^{-2} \text{ mol/L}} \]

To find the maximum concentration of \( \text{SO}_4^{2-} \) ions in a saturated solution of \( \text{M}_2\text{SO}_4 \) at 298 K, we can follow these steps: ### Step-by-Step Solution: 1. **Write the Dissociation Reaction**: The dissociation of \( \text{M}_2\text{SO}_4 \) in water can be represented as: \[ \text{M}_2\text{SO}_4 (s) \rightleftharpoons 2 \text{M}^+ (aq) + \text{SO}_4^{2-} (aq) ...
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