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Of the given anions, the strongest Brons...

Of the given anions, the strongest Bronsted base is

A

(a) `ClO^(Theta)`

B

(b) `ClO_(2)^(Theta)`

C

(c) `ClO_(3)^(Theta)`

D

(d) `ClO_(4)^(Theta)`

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The correct Answer is:
To determine which of the given anions is the strongest Brønsted base, we need to analyze the anions provided: ClO⁻, ClO₂⁻, ClO₃⁻, and ClO₄⁻. A Brønsted base is defined as a species that can accept a proton (H⁺ ion). ### Step-by-Step Solution: 1. **Understanding Brønsted Bases**: - A Brønsted base is a substance that can accept protons (H⁺ ions). Therefore, we need to consider how each anion behaves when it accepts a proton. 2. **Formation of Acids**: - When each anion accepts a proton, they form the corresponding acids: - ClO⁻ → HClO (hypochlorous acid) - ClO₂⁻ → HClO₂ (chlorous acid) - ClO₃⁻ → HClO₃ (chloric acid) - ClO₄⁻ → HClO₄ (perchloric acid) 3. **Determining Oxidation States**: - To understand the acidic strength of these acids, we need to calculate the oxidation state of chlorine in each: - In HClO: Cl is +1 - In HClO₂: Cl is +3 - In HClO₃: Cl is +5 - In HClO₄: Cl is +7 4. **Acidic Strength and Oxidation State**: - The acidic strength of these acids increases with the oxidation state of chlorine. Thus, the order of acidic strength is: - HClO₄ > HClO₃ > HClO₂ > HClO 5. **Analyzing the Bases**: - The stronger the acid, the weaker its conjugate base. Therefore, since HClO₄ is the strongest acid, ClO₄⁻ is the weakest base. Conversely, HClO is the weakest acid, making ClO⁻ the strongest base. 6. **Conclusion**: - Since ClO⁻ has the least tendency to donate H⁺ ions (it is the least acidic), it has the highest tendency to accept H⁺ ions, making it the strongest Brønsted base among the given anions. ### Final Answer: The strongest Brønsted base among the given anions is **ClO⁻**.

To determine which of the given anions is the strongest Brønsted base, we need to analyze the anions provided: ClO⁻, ClO₂⁻, ClO₃⁻, and ClO₄⁻. A Brønsted base is defined as a species that can accept a proton (H⁺ ion). ### Step-by-Step Solution: 1. **Understanding Brønsted Bases**: - A Brønsted base is a substance that can accept protons (H⁺ ions). Therefore, we need to consider how each anion behaves when it accepts a proton. 2. **Formation of Acids**: ...
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