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Mg^(2+) ions is essential for selective ...

`Mg^(2+)` ions is essential for selective precipitation of `Fe(OH)_(3)` by aqueous `NH_(3)`.

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To determine whether the statement "Mg^(2+) ions is essential for selective precipitation of Fe(OH)_(3) by aqueous NH_(3)" is true or false, we can analyze the situation step by step. ### Step-by-Step Solution: 1. **Understanding Aqueous NH3**: - Aqueous NH3 can be represented as NH4OH (ammonium hydroxide) when dissolved in water. This means that when NH3 is in solution, it acts as a weak base and can produce OH⁻ ions. 2. **Dissociation of NH4OH**: - The dissociation of NH4OH in water can be written as: \[ NH4OH \rightleftharpoons NH4^+ + OH^- \] - This reaction indicates that NH4OH produces hydroxide ions (OH⁻), which are necessary for the precipitation of metal hydroxides. 3. **Formation of Fe(OH)3**: - Iron(III) ions (Fe³⁺) can react with hydroxide ions to form iron(III) hydroxide: \[ Fe^{3+} + 3OH^- \rightarrow Fe(OH)_{3(s)} \] - This indicates that Fe(OH)3 will precipitate out of the solution when sufficient OH⁻ ions are present. 4. **Role of Mg²⁺ Ions**: - Magnesium ions (Mg²⁺) can also react with hydroxide ions to form magnesium hydroxide: \[ Mg^{2+} + 2OH^- \rightarrow Mg(OH)_{2(s)} \] - The solubility product (Ksp) of Fe(OH)3 is lower than that of Mg(OH)2, meaning Fe(OH)3 will precipitate out of solution before Mg(OH)2 when OH⁻ concentration is increased. 5. **Selective Precipitation**: - The presence of Mg²⁺ ions can affect the precipitation process. However, the key point is that the selective precipitation of Fe(OH)3 can occur in the presence of NH4OH without the need for Mg²⁺ ions. - The lower Ksp of Fe(OH)3 allows it to precipitate first, even if Mg²⁺ ions are present. 6. **Conclusion**: - Therefore, the statement that "Mg²⁺ ions is essential for selective precipitation of Fe(OH)3 by aqueous NH3" is **false**. The precipitation of Fe(OH)3 can occur independently of Mg²⁺ ions due to the differences in their solubility products. ### Final Answer: The statement is **false**.

To determine whether the statement "Mg^(2+) ions is essential for selective precipitation of Fe(OH)_(3) by aqueous NH_(3)" is true or false, we can analyze the situation step by step. ### Step-by-Step Solution: 1. **Understanding Aqueous NH3**: - Aqueous NH3 can be represented as NH4OH (ammonium hydroxide) when dissolved in water. This means that when NH3 is in solution, it acts as a weak base and can produce OH⁻ ions. 2. **Dissociation of NH4OH**: ...
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The addition of ammonium chloride to a solution containing ferric and magnesium ions is essential for selective precipitation of ferric hydroxide by aqueous ammonia.

Select the only correct option Fe(OH)_(3) sol.

Why is NH_(4)Cl essential in the precipitation of group V cations?

Consider the following statement and select correct option: (I) K_(sp) of Fe(OH)_(3) in aqueous solution is 3.8xx10^(-38) at 298 K. The concentration of Fe^(+) will increase when [H^(+)] ion concentration decreases. (II) In a mixture of NH_(4)Cl and NH_(4)OH in water, a further amountof NH_(4)Cl is added. The pH of the mixture will decreases. (III) An aqueous solution of each of the following salt (NH_(4)I,HCOOK) will be basic, acidic respectively.

Which of the following concentration of NH_(4)^(+) will be sufficient to present the precipitation of Mg(OH)_(2) form a solution which is 0.01 M MgCl_(2) and 0.1 M NH_(3)(aq) . Given that K_(sp)Mg(OH)_(2)=2.5xx10^(-11) and K_(b) for NH_(3) = 2xx10^(-5) .

At 25^(@)C , the solubility product of Mg(OH)_(2) is 1.0xx10^(-11) . At which pH , will Mg^(2+) ions start precipitating in the form of Mg(OH)_(2) from a solution of 0.001 M Mg^(2+) ions ?

A 50 mL sample of hard water containing Ca^(2+) and Mg^(2+) ions is titrated with 50 mL. 0.005 M EDTA solution at pH=10 , using eriochrome balck -T indicator to reach equivalence point. In a equal amount of hard water sample, Mg^(2+) ions are precipitated as Mg(OH)_(2) by adding suitable amount of NaOH . the solution, after precipitation of Mg(OH)_(2) , is stirred and then titrated with EDTA solution using calcon as indicator, and it requires 10 mL of above EDTA solution to reach equivalence point. a. Calculate the strength of Ca^(2+) and Mg^(2+) ions present in hard water. b. Calculate the hardness due to Ca^(2+) ions in p p m of CaCO_(3) . c. Calculate the hardness due to Mg^(2+) ions in p p m of CaCO_(3) . d. Calculate the total hardness of water in p p m of CaCO_(3) .

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The compound insoluble in aqueous NH_(3) is