Home
Class 11
CHEMISTRY
Out of the following acid base-reactions...

Out of the following acid base-reactions, reaction (b) and (c) are possible.
a. `PH_(3) + overset(o+)NH_(4) rarr overset(o+)PH_(4) +NH_(3)`
b. `NH_(3) + Poverset(o+)H_(4) rarr Noverset(o+)H_(4) + PH_(3)`
c. `(CH_(3))_(3) P + overset(o+)NH_(4) rarr (CH_(3))_(3) overset(o+)PH + NH_(3)`
d. `(CH_(3))_(3) N + PH_(4)^(o+) rarr (CH_(3))_(2) overset(o+)NH + PH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given acid-base reactions are possible, we need to analyze each reaction based on the concept of proton affinity and the relative strengths of the acids and bases involved. ### Step-by-Step Solution: 1. **Analyze Reaction (a):** - Reaction: \( PH_3 + NH_4^+ \rightarrow PH_4^+ + NH_3 \) - Here, \( NH_4^+ \) is a stronger acid than \( PH_3 \) because \( NH_4^+ \) can donate a proton more readily. - \( NH_3 \) is a stronger base than \( PH_3 \) because it can accept a proton more readily. - Therefore, this reaction is **not feasible** because \( PH_3 \) cannot act as a base against \( NH_4^+ \). 2. **Analyze Reaction (b):** - Reaction: \( NH_3 + PH_4^+ \rightarrow NH_4^+ + PH_3 \) - In this case, \( PH_4^+ \) is a stronger acid than \( NH_3 \). - \( NH_3 \) can accept a proton from \( PH_4^+ \) to form \( NH_4^+ \) and \( PH_3 \). - Therefore, this reaction is **feasible**. 3. **Analyze Reaction (c):** - Reaction: \( (CH_3)_3P + NH_4^+ \rightarrow (CH_3)_3PH + NH_3 \) - Here, \( NH_4^+ \) is again a strong acid, and \( (CH_3)_3P \) can accept a proton to form \( (CH_3)_3PH \). - Since \( (CH_3)_3P \) has a lower proton affinity compared to \( NH_3 \), this reaction is also **feasible**. 4. **Analyze Reaction (d):** - Reaction: \( (CH_3)_3N + PH_4^+ \rightarrow (CH_3)_2NH + PH_3 \) - In this case, \( PH_4^+ \) is a stronger acid than \( (CH_3)_3N \). - However, \( (CH_3)_3N \) cannot accept a proton from \( PH_4^+ \) because it has a higher proton affinity than \( PH_3 \). - Therefore, this reaction is **not feasible**. ### Conclusion: Based on the analysis: - Reaction (a) is not feasible. - Reaction (b) is feasible. - Reaction (c) is feasible. - Reaction (d) is not feasible. Thus, the statement that reactions (b) and (c) are possible is **true**.

To determine which of the given acid-base reactions are possible, we need to analyze each reaction based on the concept of proton affinity and the relative strengths of the acids and bases involved. ### Step-by-Step Solution: 1. **Analyze Reaction (a):** - Reaction: \( PH_3 + NH_4^+ \rightarrow PH_4^+ + NH_3 \) - Here, \( NH_4^+ \) is a stronger acid than \( PH_3 \) because \( NH_4^+ \) can donate a proton more readily. - \( NH_3 \) is a stronger base than \( PH_3 \) because it can accept a proton more readily. ...
Promotional Banner

Topper's Solved these Questions

  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Multiple Correct|3 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Single Correct|25 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer|10 Videos
  • HYDROGEN, WATER AND HYDROGEN PEROXIDE

    CENGAGE CHEMISTRY ENGLISH|Exercise Subjective Archive (Subjective)|3 Videos
  • ISOMERISM

    CENGAGE CHEMISTRY ENGLISH|Exercise Assertion-Reasoning Type|1 Videos

Similar Questions

Explore conceptually related problems

CH_(3)CONH_(2) overset(H_(3)O^(+))rarr Product is :

Which of the following are isoelectronic species ? overset(o+)(CH_(3))(I), overset(ɵ)(NH_(2))(II), overset(o+)(NH_(4))(III) and NH_(3) (IV)

The product D of the reaction CH_(3)Cl overset( KCN) ( rarr) ( A) overset( H_(2) O) ( rarr) (B) overset( NH_(3))(rarr) ( C ) overset( Delta)( rarr) ( D ) is

CH_(3)CH_(2)NH_(2) overset((CH_(3)CO)_(2)O)underset(Delta) to A+B , (A) and (B) are

C_(4)H_(7)OCl overset(NH_(3))rarr C_(4)H_(9)ON underset(KOH)overset(Br_(2))rarr CH_(3)CH_(2)CH_(2)NH_(2) Compound (X) is

Write the product of following reactions : (a) CH_(3)-overset(H_(3)C)overset(|)(C )=overset(CH_(3))overset(|)(C )-CH_(3) underset(Zn//H_(2)O)overset(O_(3))rarr , (b) CH_(3)-C-=C-CH_(3) underset(Zn//H_(2)O)overset(O_(3))rarr ( c) CH_(3)-C-=C-CH_(3)overset(O_(3)//H_(2)O_(2))rarr , (d) CH_(3)-overset(CH_(3))overset(|)(C )=CH-CH_(3) overset(O_(3)//H_(2)O_(2))rarr

The major product formed in the reaction CH_(3)CH = CH - overset(O)overset(||)(C ) - CH_(3)underset(H_(2)O,CH_(3)OH)overset(NaBH_(4))rarr is

CH_(3)-overset(CH_(2)CH_(3))overset(|)(CH)CH=CHCH_(3)overset(H_(3)O^(+))rarr find the product of the reaction .