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In a unit cell, atoms (A) are present at...

In a unit cell, atoms `(A)` are present at all corner lattices, `(B)` are present at alternate faces and all edge centres. Atoms `(C)` are present at face centres left from `(B)` and one at each body diagonal at disntance of `1//4th` of body diagonal from corner.
Formula of given solid is

A

`A_(3)B_(8)C_(7)`

B

`AB_(4)C_(6)`

C

`A_(6)B_(4)C_(8)`

D

`A_(2)B_(9)C_(11)`

Text Solution

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The correct Answer is:
To determine the formula of the solid based on the given arrangement of atoms in the unit cell, we will follow these steps: ### Step 1: Count the number of atoms of A Atoms A are located at all corners of the unit cell. In a cubic unit cell, there are 8 corners. Each corner atom contributes \( \frac{1}{8} \) of an atom to the unit cell. \[ \text{Number of atoms of A} = 8 \times \frac{1}{8} = 1 \] ### Step 2: Count the number of atoms of B Atoms B are located at alternate face centers and at all edge centers. - **Face Centers**: There are 6 faces in a cube, and B occupies 2 alternate faces. Each face center contributes \( \frac{1}{2} \) of an atom. \[ \text{Contribution from face centers} = 2 \times \frac{1}{2} = 1 \] - **Edge Centers**: There are 12 edges in a cube, and each edge center contributes \( \frac{1}{4} \) of an atom. \[ \text{Contribution from edge centers} = 12 \times \frac{1}{4} = 3 \] Adding these contributions together gives: \[ \text{Total number of atoms of B} = 1 + 3 = 4 \] ### Step 3: Count the number of atoms of C Atoms C are located at the face centers left from B and at the body diagonals. - **Face Centers**: Since B occupies 2 face centers, there are 4 remaining faces. Each of these contributes \( \frac{1}{2} \) of an atom. \[ \text{Contribution from remaining face centers} = 4 \times \frac{1}{2} = 2 \] - **Body Diagonals**: There are 4 body diagonals in a cube, and each body diagonal has one atom at \( \frac{1}{4} \) of the distance from the corner. \[ \text{Contribution from body diagonals} = 4 \times 1 = 4 \] Adding these contributions together gives: \[ \text{Total number of atoms of C} = 2 + 4 = 6 \] ### Step 4: Write the empirical formula Now that we have the counts for each atom type: - Number of A = 1 - Number of B = 4 - Number of C = 6 The empirical formula of the solid can be written as: \[ \text{Formula} = A_1B_4C_6 \quad \text{or simply} \quad ABC_4C_6 \] ### Final Answer The formula of the given solid is \( A_1B_4C_6 \). ---

To determine the formula of the solid based on the given arrangement of atoms in the unit cell, we will follow these steps: ### Step 1: Count the number of atoms of A Atoms A are located at all corners of the unit cell. In a cubic unit cell, there are 8 corners. Each corner atom contributes \( \frac{1}{8} \) of an atom to the unit cell. \[ \text{Number of atoms of A} = 8 \times \frac{1}{8} = 1 \] ...
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